Effect of the Nature of the Catalyst on Catalytic Activity and Selectivity in the Formaldehyde Hydrogenation

被引：0

作者：

Tarasov, A. L. ^{[1
]}

机构：

[1] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2018年 / 92卷 / 09期

基金：

俄罗斯科学基金会;

关键词：

formaldehyde; methanol; ethanol; formic acid; hydrogenation; OXIDATION; ADSORPTION; PARTICLES; ZEOLITES; SYSTEMS; SITES; AU;

D O I：

10.1134/S0036024418090297

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect the nature of the carrier and supported metal on the activity and selectivity of the catalyst in the reaction of formaldehyde hydrogenation to methanol is studied. The formation of such oxygenates as ethanol, formic acid, and diethyl formal is observed. It is found that ethanol forms on Fe-containing alloyed catalyst, while formic acid forms on the catalysts containing Au. Thermodynamic calculations are performed for a series of side reactions that confirm the formation of the resulting oxygenates.

引用

页码：1670 / 1674

页数：5

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