Electrostatic interaction between cationic calix[4]pyrroles and anionic porphyrins in water

被引：4
|
作者：
Garg, Bhaskar [1 ]
Bisht, Tanuja [1 ]
Chauhan, Shive Murat Singh [1 ]
机构：
[1] Univ Delhi, Dept Chem, Bioorgan Res Lab, Delhi 110007, India
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2010年 / 67卷 / 1-2期
关键词：
Thiacyclohexanocalix[4]pyrroles; Self-assembly; Ionic interactions; Anionic porphyrins; Absorption spectroscopy; BINDING; CALIXPYRROLES; CHEMISTRY;
D O I：
10.1007/s10847-009-9697-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The formation and characterization of molecular assemblies resulting from mixing of solutions of tetracationic calix[4]pyrroles and tetraanionic porphyrins in water are reported. The self-assembly of the complementary building blocks was quantitatively studied by UV-vis, H-1 NMR, Fluorescence and ESI-MS. Binding constants calculated by absorption spectroscopic titrations were in the range of 10(3)-10(5) M-1. The results indicate that the cationic thiacalix[4]pyrroles show greater binding affinity towards metal free porphyrins than metalloporphyrins under neutral conditions.
引用
收藏
页码：241 / 246
页数：6
相关论文
共 50 条
  • [31] Study on the interaction between anionic and cationic latex particles and Portland cement
    Plank, J.
    Gretz, M.
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 330 (2-3) : 227 - 233
  • [32] STUDIES ON THE INTERACTION BETWEEN NUCLEIC-ACIDS AND CATIONIC PORPHYRINS .2.
    PETHO, G
    ELLIOTT, NB
    LIN, M
    MARZILLI, LG
    KIM, MS
    DIXON, DW
    MAGYAR KEMIAI FOLYOIRAT, 1993, 99 (10): : 417 - 419
  • [33] TRIPLET ELECTRON-SPIN-RESONANCE STUDY OF DIMERIZATION OF CATIONIC AND ANIONIC WATER-SOLUBLE PORPHYRINS
    VANWILLIGEN, H
    DAS, U
    OJADI, E
    LINSCHITZ, H
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (25) : 7784 - 7785
  • [34] Water-Soluble Aryl- and Super Aryl-Extended Calix[4]pyrroles
    Aragay, Gemma
    Ballester, Pablo
    ISRAEL JOURNAL OF CHEMISTRY, 2024, 64 (6-7)
  • [35] Ultrafast photophysical study of self-assembled complexes between anionic porphyrins and cationic phthalocyanines.
    Gusev, A
    Danilov, E
    Rodgers, MAJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U206 - U206
  • [36] New subsidiary interaction mode of counteranions with the periphery cavity of calix[4]pyrroles binding with the anion subunits
    Liu, K
    Guo, Y
    Xu, J
    Shao, SJ
    Jiang, SX
    CHINESE CHEMICAL LETTERS, 2006, 17 (03) : 387 - 390
  • [37] New Subsidiary Interaction Mode of Counteranions with the Periphery Cavity of Calix[4]pyrroles Binding with the Anion Subunits
    Kai LIU1
    Chinese Chemical Letters, 2006, (03) : 387 - 390
  • [38] Spherical micelle transition behaviors at different composition of calix[4]arene by the electrostatic interaction
    Lee, Ji Ha
    Fujii, Shota
    Takahashi, Rintaro
    Sakurai, Kazuo
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [39] Interaction between bromopyrogallol red anionic dye and cationic surfactants and its application in the determination of cationic surfactants
    Huang, XR
    Han, SH
    Zhang, WJ
    Yin, YQ
    Jie, NQ
    Huang, JP
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1997, 36 (12): : 1097 - 1100
  • [40] Interaction between a cationic polymethacrylate (Eudragit E100) and anionic drugs
    Quinteros, Daniela A.
    Rigo, Veronica Ramirez
    Kairuz, Alvaro E. Jimenez
    Olivera, Maria E.
    Manzo, Ruben H.
    Allemandi, Daniel A.
    EUROPEAN JOURNAL OF PHARMACEUTICAL SCIENCES, 2008, 33 (01) : 72 - 79
12345