A biferrocenium salt containing paramagnetic tetracyanoquinodimethane hexamers: charge disproportionation via donor-acceptor interactions

被引：3

作者：

Mochida, Tomoyuki ^{[1
]}

Funasako, Yusuke ^{[1
,2
]}

Takahashi, Kazuyuki ^{[1
]}

Inokuchi, Makoto ^{[2
]}

Sakurai, Takahiro ^{[3
]}

Ikeda, Shohei ^{[4
]}

Ohta, Hitoshi ^{[5
]}

Mori, Hatsumi ^{[6
]}

Uruichi, Mikio ^{[7
]}

机构：

[1] Kobe Univ, Grad Sch Sci, Dept Chem, Nada Ku, Kobe, Hyogo 6578501, Japan

[2] Tokyo Univ Sci, Fac Engn, Dept Appl Chem, Onoda, Yamaguchi 7560884, Japan

[3] Kobe Univ, Ctr Supports Res & Educ Activ, Kobe, Hyogo 6578501, Japan

[4] Kobe Univ, Grad Sch Sci, Dept Phys, Kobe, Hyogo 6578501, Japan

[5] Kobe Univ, Mol Photosci Res Ctr, Kobe, Hyogo 6578501, Japan

[6] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan

[7] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 87期

关键词：

FREE-RADICAL SALTS; MIXED-VALENCE STATES; ELECTRON-TRANSFER; CRYSTAL-STRUCTURES; PHASE-TRANSITION; MAGNETIC-PROPERTIES; TCNQ; COMPLEXES; MONOVALENT; MOSSBAUER;

D O I：

10.1039/c4cc06888b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Dineopentyl-biferrocene](2)[CI(1)TCNQ](7), which has an unprecedented high donor-acceptor ratio of 2:7, contains a linear paramagnetic hexamer of Cl(1)TCNQ. Both the donor and acceptor molecules exhibit charge disproportionation in the crystal through mutual electrostatic interactions.

引用

页码：13370 / 13372

页数：3