A biferrocenium salt containing paramagnetic tetracyanoquinodimethane hexamers: charge disproportionation via donor-acceptor interactions

被引：3
|
作者：
Mochida, Tomoyuki [1 ]
Funasako, Yusuke [1 ,2 ]
Takahashi, Kazuyuki [1 ]
Inokuchi, Makoto [2 ]
Sakurai, Takahiro [3 ]
Ikeda, Shohei [4 ]
Ohta, Hitoshi [5 ]
Mori, Hatsumi [6 ]
Uruichi, Mikio [7 ]
机构：
[1] Kobe Univ, Grad Sch Sci, Dept Chem, Nada Ku, Kobe, Hyogo 6578501, Japan
[2] Tokyo Univ Sci, Fac Engn, Dept Appl Chem, Onoda, Yamaguchi 7560884, Japan
[3] Kobe Univ, Ctr Supports Res & Educ Activ, Kobe, Hyogo 6578501, Japan
[4] Kobe Univ, Grad Sch Sci, Dept Phys, Kobe, Hyogo 6578501, Japan
[5] Kobe Univ, Mol Photosci Res Ctr, Kobe, Hyogo 6578501, Japan
[6] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan
[7] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 87期
关键词：
FREE-RADICAL SALTS; MIXED-VALENCE STATES; ELECTRON-TRANSFER; CRYSTAL-STRUCTURES; PHASE-TRANSITION; MAGNETIC-PROPERTIES; TCNQ; COMPLEXES; MONOVALENT; MOSSBAUER;
D O I：
10.1039/c4cc06888b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[Dineopentyl-biferrocene](2)[CI(1)TCNQ](7), which has an unprecedented high donor-acceptor ratio of 2:7, contains a linear paramagnetic hexamer of Cl(1)TCNQ. Both the donor and acceptor molecules exhibit charge disproportionation in the crystal through mutual electrostatic interactions.
引用
收藏
页码：13370 / 13372
页数：3
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