Mechanical model to evaluate the effect of the dispersion in nanocomposites

被引:275
作者
Guzman de Villoria, R. [1 ]
Miravete, A. [1 ]
机构
[1] Univ Zaragoza, Dept Mech Engn, Zaragoza 50018, Spain
关键词
micromechanical modeling; nanocomposite; mechanical properties; carbon nanotubes;
D O I
10.1016/j.actamat.2007.01.007
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A key parameter in taking advantage of the exceptional mechanical and physical properties of carbon nanotubes (CNT) is getting a homogeneous dispersion of the nanofiller in the matrix. Micromechanical models are used to predict the properties of composites, but in most cases the calculated results are not comparable with those from experimentation. In the ease of epoxy matrices, poorly dispersed CNT are obtained, as has been observed by scanning electron microscopy. The influence of the dispersion in nanocomposite stiffness is estimated developing a new micromechanical model. Several micromechanical models and experimental results are compared with this new model, showing that the latter has better agreement with mechanical tests. In addition, this mathematical formulation could be used with other reinforcements that are poorly dispersed, not only with CNT. (c) 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:3025 / 3031
页数:7
相关论文
共 17 条
  • [1] *AENOR, 1996, 5272 UNEEN ISO
  • [2] *AENOR, 1996, 5211 UNEEN ISO
  • [3] [Anonymous], 1991, MECH COMPOSITE MAT
  • [4] Detachment of nanotubes from a polymer matrix
    Cooper, CA
    Cohen, SR
    Barber, AH
    Wagner, HD
    [J]. APPLIED PHYSICS LETTERS, 2002, 81 (20) : 3873 - 3875
  • [5] Distribution and alignment of carbon nanotubes and nanofibrils in a polymer matrix
    Cooper, CA
    Ravich, D
    Lips, D
    Mayer, J
    Wagner, HD
    [J]. COMPOSITES SCIENCE AND TECHNOLOGY, 2002, 62 (7-8) : 1105 - 1112
  • [6] Mechanical properties of SWNT/epoxy composites using two different curing cycles
    de Villoria, RG
    Miravete, A
    Cuartero, J
    Chiminelli, A
    Tolosana, N
    [J]. COMPOSITES PART B-ENGINEERING, 2006, 37 (4-5) : 273 - 277
  • [7] Surface modified multi-walled carbon nanotubes in CNT/epoxy-composites
    Gojny, FH
    Nastalczyk, J
    Roslaniec, Z
    Schulte, K
    [J]. CHEMICAL PHYSICS LETTERS, 2003, 370 (5-6) : 820 - 824
  • [8] Carbon nanotube-reinforced epoxy-compo sites:: enhanced stiffness and fracture toughness at low nanotube content
    Gojny, FH
    Wichmann, MHG
    Köpke, U
    Fiedler, B
    Schulte, K
    [J]. COMPOSITES SCIENCE AND TECHNOLOGY, 2004, 64 (15) : 2363 - 2371
  • [9] HELICAL MICROTUBULES OF GRAPHITIC CARBON
    IIJIMA, S
    [J]. NATURE, 1991, 354 (6348) : 56 - 58
  • [10] Mechanical characterization of carbon nanotube composite materials
    Laborde-Lahoz, P
    Maser, W
    Martínez, T
    Benito, A
    Seeger, T
    Cano, P
    de Villoria, RG
    Miravete, A
    [J]. MECHANICS OF ADVANCED MATERIALS AND STRUCTURES, 2005, 12 (01) : 13 - 19