Must an N-Heterocyclic Carbene Be a Terminal Ligand?

被引：33

作者：

Han, Xiaoyan ^{[2
]}

Koh, Lip-Lin ^{[2
]}

Liu, Zhi-Pan ^{[1
]}

Weng, Zhiqiang ^{[2
,4
]}

Hor, T. S. Andy ^{[2
,3
]}

机构：

[1] Fudan Univ, Dept Chem, MOE Key Lab Computat Phys Sci, Shanghai 200433, Peoples R China

[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

[3] Agcy Sci Technol & Res, Inst Mat Res & Engn, Singapore 117602, Singapore

[4] Fuzhou Univ, Coll Chem & Chem Engn, Fujian 350108, Peoples R China

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 11期

关键词：

STRUCTURAL-CHARACTERIZATION; COMPLEXES; COORDINATION; REACTIVITY; PHOSPHANES;

D O I：

10.1021/om100277f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A "stand-alone" NHC carbene without a heterocyclic secondary donor has been crystallographically identified together with its terminal counterpart, with both coordination isomers cocrystallized in a single crystal.

引用

页码：2403 / 2405

页数：3

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