Solution Combustion Synthesis of Cr2O3 Nanoparticles and Derived PVA/Cr2O3 Nanocomposites-Positron Annihilation Spectroscopic Study

被引:8
作者
Prashanth, K. S. [1 ]
Mahesh, S. S. [2 ]
Prakash, M. B. Nanda [3 ]
Munirathnamma, L. M. [3 ]
Ningaraju, S. [3 ]
Ravikumar, H. B. [3 ]
Somashekar, R. S. [3 ]
Nagabhushana, B. M. [4 ]
机构
[1] New Horizon Coll Engn, Dept Phys, Bangalore 560103, Karnataka, India
[2] Acharya Inst Technol, Dept Phys, Bangalore 560107, Karnataka, India
[3] Univ Mysore, Dept Studies Phys, Mysore 570006, Karnataka, India
[4] MS Ramiah Inst Technol, Dept Chem, Bangalore 560064, Karnataka, India
关键词
Solution combustion method; Nanocomposites; PALS; POLY(VINYL ALCOHOL) NANOCOMPOSITES; MOLECULAR-WEIGHT; TEMPERATURE; COMPOSITES; DEPENDENCE; BLENDS;
D O I
10.1016/j.matpr.2016.11.008
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Solution combustion based nanosize chromium oxide nanoparticles blended PVA/Cr2O3/NaCl nanocomposite thin films of various weight percentages were synthesized using solvent cast method. The FTIR and SEM results are in confirmation with XRD results indicating the formation of nanocomposites. Positron Life time spectroscopy (PALS) are used for the microstructural characterization in the (PVA)/Cr2O3/NaCl polymer nanocomposites. The PALS results show that the free volume size and o-Ps lifetime (tau(3)) increases up to 4 wt% decreases after 6 wt% The decreased o-Ps lifetime (tau(3)) indicates the inhibition of o-Ps formation upon incorporation of Chromium Oxide nano particles into PVA matrix (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3646 / 3651
页数:6
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