Probing Vibrational Anisotropy with Nuclear Resonance Vibrational Spectroscopy

被引：27

作者：

Pavlik, Jeffrey W. ^{[1
]}

Barabanschikov, Alexander ^{[2
,3
]}

Oliver, Allen G. ^{[1
]}

Alp, E. Ercan ^{[4
]}

Sturhahn, Wolfgang ^{[4
]}

Zhao, Jiyong ^{[4
]}

Sage, J. Timothy ^{[2
,3
]}

Scheidt, W. Robert ^{[1
]}

机构：

[1] Univ Notre Dame, Dept Chem & Biochem, Notre Dame, IN 46556 USA

[2] Northeastern Univ, Dept Phys, Boston, MA 02115 USA

[3] Northeastern Univ, Ctr Interdisciplinary Res Complex Syst, Boston, MA 02115 USA

[4] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 26期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

iron porphyrinates; Mossbauer spectroscopy; NO complexes; NRVS (nuclear resonance vibrational spectroscopy); SOLUBLE GUANYLYL CYCLASE; HEME NITROSYLS; AXIAL LIGAND; DYNAMICS; IRON; NO; DERIVATIVES; PORPHYRINS; MECHANISM; PROTEINS;

D O I：

10.1002/anie.201000928

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) In-depth probing: A NRVS single-crystal study (NRVS = nuclear resonance vibrational spectroscopy) has provided detailed information on the in-plane modes of nitrosyl iron porphyrinate [Fe(oep)(NO)] (see picture; oep=octaethylporphyrin). The axial nitrosyl ligand controls the direction of the in-plane iron motion. © 2010 Wlley-VCH Verlag GmbH &. Co. KGaA, Weinheim www.angewandte.org.

引用

页码：4400 / 4404

页数：5

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