Synthesis, structure and gas adsorption properties of coordination polymers based on mixed imidazole-containing ligands and carboxylate ligands

被引：6

作者：

Zhao, Jiang-Lin ^{[1
]}

Wu, Chong ^{[2
]}

Redshaw, Carl ^{[3
]}

Jin, Zongwen ^{[1
]}

机构：

[1] Chinese Acad Sci, Shenzhen Inst Adv Technol, Inst Biomed & Hlth Engn, 1068 Xueyuan Ave, Shenzhen 518055, Peoples R China

[2] Guizhou Univ Tradit Chinese Med, Coll Pharm, Guiyang 550025, Peoples R China

[3] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England

来源：

INORGANICA CHIMICA ACTA | 2021年 / 517卷

基金：

英国工程与自然科学研究理事会;

关键词：

METAL-ORGANIC FRAMEWORKS; CADMIUM(II) COMPLEXES; REACTION TEMPERATURE; CRYSTAL-STRUCTURES; ASSEMBLIES; PLATFORMS; ZINC(II); SORPTION; CENTERS; PH;

D O I：

10.1016/j.ica.2020.120193

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Herein, we report the synthesis of two novel coordination polymers using a combination of imidazole-containing ligands, namely 1,3,5-tris((1H-imidazol-1-yl) methyl)benzene (L-1) and 3,3',5,5' -tetra(1H-imidazol-1-yl)-1,1'-biphenyl (L-2) and a carboxylate ligand derived from 4,4'-biphenyldicarboxylic acid (H2BPDC). The structures of the two coordination polymers [Ni(L-1)(BPDC)]center dot 2H(2)O (1 center dot 2H(2)O), which exhibits a 2-fold interpenetrated 3D -> 3D architecture, and {[Co(CH3OH)(2)(L-2)(0.5)(BPDC)] (2) possessing a 2D framework, have been determined. Moreover, the gas adsorption properties of 1 and 2 have been investigated.

引用

页数：6

共 45 条

[1] Luminescent metal-organic frameworks [J].