Air-assisted flow and two-step spin-coating for highly efficient CH3NH3PbI3 perovskite solar cells

被引:25
作者
Eze, Vincent Obiozo [1 ]
Lei, Binglong [1 ]
Mori, Tatsuo [1 ]
机构
[1] Aichi Inst Technol, Dept Elect & Elect Engn, Toyota, Aichi 4700392, Japan
关键词
TEMPERATURE; DEPOSITION; ELECTRON; LENGTHS; GROWTH; LIGHT; FILMS; SIZE;
D O I
10.7567/JJAP.55.02BF08
中图分类号
O59 [应用物理学];
学科分类号
摘要
There is a multitude of reports on different methods of fabricating organic-inorganic halide perovskite films for high-efficiency solar cells. In this study, planar heterojunction (PHJ) CH3NH3PbI3 perovskite solar cells were prepared by the two-step spin-coating method. The uniformity of the perovskite light-absorbing layer is enhanced by air-assisted flow (AAF). We compared the photovoltaic performance characteristics of films prepared with and without AAF. Perovskite solar cells constructed without AAF showed a power conversion efficiency (PCE) of 8.67%, whereas a higher PCE of 13.28% was obtained with an AAF-based perovskite solar cell. Our study presents a useful technique for preparing high-quality perovskite films. (C) 2016 The Japan Society of Applied Physics
引用
收藏
页数:7
相关论文
共 31 条
[21]   New Light on an Old Story: Perovskites Go Solar [J].
Lotsch, Bettina V. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (03) :635-637
[22]  
Malinkiewicz O, 2014, NAT PHOTONICS, V8, P128, DOI [10.1038/NPHOTON.2013.341, 10.1038/nphoton.2013.341]
[23]   Unravelling the mechanism of photoinduced charge transfer processes in lead iodide perovskite solar cells [J].
Marchioro, Arianna ;
Teuscher, Joel ;
Friedrich, Dennis ;
Kunst, Marinus ;
van de Krol, Roel ;
Moehl, Thomas ;
Graetzel, Michael ;
Moser, Jacques-E .
NATURE PHOTONICS, 2014, 8 (03) :250-255
[24]   Thin film deposition of organic-inorganic hybrid materials using a single source thermal ablation technique [J].
Mitzi, DB ;
Prikas, MT ;
Chondroudis, K .
CHEMISTRY OF MATERIALS, 1999, 11 (03) :542-+
[25]   Perovskite solar cells and large area modules (100 cm2) based on an air flow-assisted PbI2 blade coating deposition process [J].
Razza, Stefano ;
Di Giacomo, Francesco ;
Matteocci, Fabio ;
Cina, Lucio ;
Palma, Alessandro Lorenzo ;
Casaluci, Simone ;
Cameron, Petra ;
D'Epifanio, Alessandra ;
Licoccia, Silvia ;
Reale, Andrea ;
Brown, Thomas M. ;
Di Carlo, Aldo .
JOURNAL OF POWER SOURCES, 2015, 277 :286-291
[26]   FUNDAMENTAL ABSORPTION-EDGE IN PBI2-KI ALLOYS [J].
SALAU, AM .
SOLAR ENERGY MATERIALS, 1980, 2 (03) :327-332
[27]   Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber [J].
Stranks, Samuel D. ;
Eperon, Giles E. ;
Grancini, Giulia ;
Menelaou, Christopher ;
Alcocer, Marcelo J. P. ;
Leijtens, Tomas ;
Herz, Laura M. ;
Petrozza, Annamaria ;
Snaith, Henry J. .
SCIENCE, 2013, 342 (6156) :341-344
[28]   High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites [J].
Wehrenfennig, Christian ;
Eperon, Giles E. ;
Johnston, Michael B. ;
Snaith, Henry J. ;
Herz, Laura M. .
ADVANCED MATERIALS, 2014, 26 (10) :1584-1589
[29]   High Efficiency and Robust Performance of Organo Lead Perovskite Solar Cells with Large Grain Absorbers Prepared in Ambient Air Conditions [J].
Wu, Kuan-Lin ;
Kogo, Atsushi ;
Sakai, Nobuya ;
Ikegami, Masashi ;
Miyasaka, Tsutomu .
CHEMISTRY LETTERS, 2015, 44 (03) :321-323
[30]   Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3 [J].
Xing, Guichuan ;
Mathews, Nripan ;
Sun, Shuangyong ;
Lim, Swee Sien ;
Lam, Yeng Ming ;
Graetzel, Michael ;
Mhaisalkar, Subodh ;
Sum, Tze Chien .
SCIENCE, 2013, 342 (6156) :344-347