Beryllium bis(diazaborolyl): old neighbors finally shake hands

被引：51

作者：

Arnold, T. ^{[1
]}

Braunschweig, H. ^{[1
]}

Ewing, W. C. ^{[1
]}

Kramer, T. ^{[1
]}

Mies, J. ^{[1
]}

Schuster, J. K. ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 04期

关键词：

CHEMISTRY; BORYLLITHIUM; REACTIVITY; INSERTION; COMPLEX; BOND; FORM;

D O I：

10.1039/c4cc08519a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a linear beryllium bis(diazaborolyl) compound featuring the first non-cluster bond between boron and beryllium has been achieved through the reaction of Yamashita's lithium diazaborolide and BeCl2. In accord with the established chemistry of beryllium, the bonding is polar covalent in character, as determined by structural and spectroscopic analysis, as well as reactivity studies.

引用

页码：737 / 740

页数：4

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