Beryllium bis(diazaborolyl): old neighbors finally shake hands

被引：51

作者：

Arnold, T. ^{[1
]}

Braunschweig, H. ^{[1
]}

Ewing, W. C. ^{[1
]}

Kramer, T. ^{[1
]}

Mies, J. ^{[1
]}

Schuster, J. K. ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 04期

关键词：

CHEMISTRY; BORYLLITHIUM; REACTIVITY; INSERTION; COMPLEX; BOND; FORM;

D O I：

10.1039/c4cc08519a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of a linear beryllium bis(diazaborolyl) compound featuring the first non-cluster bond between boron and beryllium has been achieved through the reaction of Yamashita's lithium diazaborolide and BeCl2. In accord with the established chemistry of beryllium, the bonding is polar covalent in character, as determined by structural and spectroscopic analysis, as well as reactivity studies.

引用

页码：737 / 740

页数：4

共 32 条

[1]

[Anonymous], 1972, ADV INORG CHEM

[2] CHEMICAL SHIELDING TENSER OF A CARBENE [J].

ARDUENGO, AJ ;

DIXON, DA ;

KUMASHIRO, KK ;

LEE, C ;

POWER, WP ;

ZILM, KW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (14) :6361-6367

[3]

ARORA M, 1969, INDIAN J CHEM, V7, P399

[4] Beryllium-Induced C?N Bond Activation and Ring Opening of an N-Heterocyclic Carbene [J].

Arrowsmith, Merle ;

Hill, Michael S. ;

Kociok-Koehn, Gabriele ;

MacDougall, Dugald J. ;

Mahon, Mary F. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (09) :2098-2100

[5] A linear, anionic dimetalloborylene complex [J].

Braunschweig, Holger ;

Burzler, Michael ;

Dewhurst, Rian D. ;

Radacki, Krzysztof .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (30) :5650-5653

[6] Synthesis and Structure of a Carbene-Stabilized π-Boryl Anion [J].

Braunschweig, Holger ;

Chiu, Ching-Wen ;

Radacki, Krzysztof ;

Kupfer, Thomas .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (11) :2041-2044

[7] A Dimethylgallium Boryl Complex and Its Methyllithium Addition Compound [J].

Dettenrieder, Nicole ;

Schaedle, Christoph ;

Maichle-Moessmer, Caecilia ;

Sirsch, Peter ;

Anwander, Reiner .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (03) :886-889

[8] Organoaluminum Boryl Complexes [J].

Dettenrieder, Nicole ;

Dietrich, H. Martin ;

Schaedle, Christoph ;

Maichle-Moessmer, Caecilia ;

Tornroos, Karl W. ;

Anwander, Reiner .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (18) :4461-4465

[9] INSERTION OF BERYLLIUM INTO A BORON-BORON BOND - SYNTHESIS OF MU-[ETA-5-CYCLOPENTADIENYLBERYLLA]OCTAHYDROPENTABORATE, MU-[ETA-5-(C5H5)BE]B5H8 [J].

GAINES, DF ;

COLESON, KM ;

CALABRESE, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (14) :3979-3980

[10] CHEMISTRY OF 2-BERYLLA-NIDO-HEXABORANE(11) COMPOUNDS - INSERTION OF BERYLLIUM INTO A BORANE CAGE [J].

GAINES, DF ;

WALSH, JL .

INORGANIC CHEMISTRY, 1978, 17 (05) :1238-1241

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