Single-Electron Transfer Driven Cyanide Sensing: A New Multimodal Approach

被引：129
|
作者：
Ajayakumar, M. R. [1 ]
Mukhopadhyay, Pritam [1 ]
Yadav, Sarita
Ghosh, Subhasis
机构：
[1] Jawaharlal Nehru Univ, Sch Phys Sci, Supramol & Mat Chem Lab, New Delhi 110067, India
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 11期
关键词：
ANION RECOGNITION; FLUORESCENT; CHEMODOSIMETERS; BORANES; IMIDE; IONS; DYES;
D O I：
10.1021/ol1008558
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new SET-driven reaction-based strategy is reported for sensing of cyanide with indicators having low LUMO levels. The cyanide-specific reaction produces an air-stable radical anion marker and by virtue of its spin, charge, signal outputs. High selectivity and sensitivity (0.2-16 mu M) were observed when compared to other reducing anions. This new indicator system exhibits regenerability and dip-stick sensing, and fabrication of an electronic sensing device for cyanide is demonstrated.
引用
收藏
页码：2646 / 2649
页数：4
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