Direct Synthesis of Dimethyl Ether (DME) from Syngas

被引:0
作者
Takeishi, Kaoru [1 ]
Akaike, Yoshimi [1 ]
机构
[1] Shizuoka Univ, Dept Mat Sci & Chem Engn, Naka Ku, 3-5-1 Jouhoku, Hamamatsu, Shizuoka 4328561, Japan
来源
RECENT ADVANCES IN ENERGY AND ENVIRONMENT | 2010年
关键词
Dimethyl ether; DME; hydrogen; clean fuel; catalyst; sol-gel method; alumina; copper; direct synthesis; syngas;
D O I
暂无
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
We have developed appropriate and excellent catalysts for direct DME synthesis. The catalysts, Cu-Zn/Al2O3 catalysts prepared by the sol-gel method, produce DME with high DME activity and high DME selectivity under milder reaction temperature and pressure compared with the usual direct DME synthesis catalysts (mixed catalysts of methanol synthesis catalysts and methanol dehydration catalysts). It will be the reason why the methanol synthesis active sites (copper) and the methanol dehydration active sites (alumina) on the sol-gel Cu/Al2O3 catalysts exist closer than those of the mixed catalysts.
引用
收藏
页码:408 / +
页数:3
相关论文
共 9 条
[1]  
Fleisch TH, 1997, STUD SURF SCI CATAL, V107, P117
[2]   Steam reforming of dimethyl ether [J].
Takeishi, K ;
Suzuki, H .
APPLIED CATALYSIS A-GENERAL, 2004, 260 (01) :111-117
[3]  
TAKEISHI K, Patent No. 3951127
[4]  
TAKEISHI K, Patent No. 7241718
[5]   Dimethyl ether and catalyst development for production from syngas [J].
Takeishi, Kaoru .
BIOFUELS-UK, 2010, 1 (01) :217-226
[6]  
1992, Patent No. 1992264046
[7]  
1991, Patent No. 1991181435
[8]  
1993, Patent No. 9310069
[9]  
1991, Patent No. 19918446