Combustion Kinetics and Emission Characteristics of Polycyclic Aromatic Hydrocarbons from Polylactic Acid Combustion

被引:21
作者
Chien, Yi-Chi [1 ]
Liang, Chenju [2 ]
Liu, Shou-Heng [3 ]
Yang, Shu-Hua [1 ]
机构
[1] Fooyin Univ, Dept Environm Engn & Sci, Kaohsiung, Taiwan
[2] Natl Chung Hsing Univ, Dept Environm Engn, Taichung 40227, Taiwan
[3] Natl Kaohsiung Univ Appl Sci, Dept Chem & Mat Engn, Kaohsiung 807, Taiwan
来源
JOURNAL OF THE AIR & WASTE MANAGEMENT ASSOCIATION | 2010年 / 60卷 / 07期
关键词
THERMAL-DEGRADATION; POLY(LACTIC ACID); ORGANIC-COMPOUNDS; WASTE PLASTICS; PAH EMISSION; PARTICULATE; PYROLYSIS; POLYSTYRENE; ATMOSPHERE; PRODUCTS;
D O I
10.3155/1047-3289.60.7.849
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study investigates the combustion kinetics and emission factors of 16 U.S. Environmental Protection Agency priority polycyclic aromatic hydrocarbons (PAHs) in polylactic acid (PLA) combustion. Experimentally, two reactions are involved in the PLA combustion process that potentially result in the release of lactide, acetaldehyde, and n-hexaldehyde. The products may continuously be oxidized to form carbon dioxide (CO(2)) and some PAHs produced because of incomplete combustion. The analytical results indicate that the emission factors for PAHs are in the range of not detectable to 98.04 mu g/g. The emission factors are much lower than those of poly(ethylene terephalate) (PET) and other combustion of plastics. Results from this work suggest that combustion is a good choice for waste PLA disposal.
引用
收藏
页码:849 / 855
页数:7
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