Ring-opening polymerization of L-lactide catalyzed by a biocompatible calcium complex

被引：65

作者：

Chen, Hsuan-Ying ^{[1
]}

Tang, Hui-Yi ^{[1
]}

Lin, Chu-Chieh ^{[1
]}

机构：

[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan

来源：

POLYMER | 2007年 / 48卷 / 08期

关键词：

calcium; catalysis; L-lactide;

D O I：

10.1016/j.polymer.2007.02.030

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel calcium complex, [(DAIP)(2)Ca](2) (where DAIP-H = 2-[(2-dimethylamino)methyl]phenol, is prepared in a one flask reaction by condensation of Ca(OMe)(2) with DAIP-H in toluene/THF Experimental results show that in the presence of various alcohols, [(DAIP)(2)Ca](2) efficiently initiates the ring-opening polymerization Of L-lactide in a controlled fashion, yielding polymers with expectative molecular weight and low polydispersity indexes. Furthermore, kinetic studies show a first-order dependency on both [LA] and [BnOH]. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：2257 / 2262

页数：6

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