Polyglycerol-derived amphiphiles for single walled carbon nanotube suspension

被引：31

作者：

Setaro, A. ^{[1
]}

Popeney, C. S. ^{[2
]}

Trappmann, B. ^{[2
]}

Datsyuk, V. ^{[1
]}

Haag, R. ^{[2
]}

Reich, S. ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Expt Phys, D-14195 Berlin, Germany

[2] Free Univ Berlin, Inst Chem & Biochem Organ Chem, D-14195 Berlin, Germany

来源：

CHEMICAL PHYSICS LETTERS | 2010年 / 493卷 / 1-3期

关键词：

D O I：

10.1016/j.cplett.2010.05.052

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Inspired by the commercially available SDS surfactant, a new polyglycerol-derived amphiphile has been synthesized for functionalizing carbon nanotubes. SDS' sulphate group was replaced by a polyglycerol dendron. The steric hindrance offered by the dendrons makes the compound much more efficient than SDS in isolating and stabilizing nanotubes in solution. Further amphiphiles have been synthesized by adding small aromatic moieties between head and tail groups. We show that this addition leads to selective interaction between surfactants and carbon nanotubes. Excitation photoluminescence and optical absorption spectroscopy analysis confirm the change in the distribution of nanotubes' chiralities in suspension, depending on the amphiphile. (C) 2010 Elsevier B. V. All rights reserved.

引用

页码：147 / 150

页数：4

共 12 条

[1]

[Anonymous], 2004, Carbon Nanotubes: Basic Concepts and Physical Properties

[2] Sorting carbon nanotubes by electronic structure using density differentiation [J].

Arnold, Michael S. ;

Green, Alexander A. ;

Hulvat, James F. ;

Stupp, Samuel I. ;

Hersam, Mark C. .

NATURE NANOTECHNOLOGY, 2006, 1 (01) :60-65

[3] Structure-assigned optical spectra of single-walled carbon nanotubes [J].

Bachilo, SM ;

Strano, MS ;

Kittrell, C ;

Hauge, RH ;

Smalley, RE ;

Weisman, RB .

SCIENCE, 2002, 298 (5602) :2361-2366

[4] Adenovirus-based vascular endothelial growth factor gene delivery to human pancreatic islets [J].

Cheng, K ;

Fraga, D ;

Zhang, C ;

Kotb, M ;

Gaber, AO ;

Guntaka, RV ;

Mahato, RI .

GENE THERAPY, 2004, 11 (14) :1105-1116

[5] Solvatochromism in single-walled carbon nanotubes [J].

Choi, Jong Hyun ;

Strano, Michael S. .

APPLIED PHYSICS LETTERS, 2007, 90 (22)

[6] HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].

IIJIMA, S .

NATURE, 1991, 354 (6348) :56-58

[7] Selection of carbon nanotubes with specific chiralities using helical assemblies of flavin mononucleotide [J].

Ju, Sang-Yong ;

Doll, Jonathan ;

Sharma, Ity ;

Papadimitrakopoulos, Fotios .

NATURE NANOTECHNOLOGY, 2008, 3 (06) :356-362

[8] Band gap fluorescence from individual single-walled carbon nanotubes [J].

O'Connell, MJ ;

Bachilo, SM ;

Huffman, CB ;

Moore, VC ;

Strano, MS ;

Haroz, EH ;

Rialon, KL ;

Boul, PJ ;

Noon, WH ;

Kittrell, C ;

Ma, JP ;

Hauge, RH ;

Weisman, RB ;

Smalley, RE .

SCIENCE, 2002, 297 (5581) :593-596

[9] Electronic structure control of single-walled carbon nanotube functionalization [J].

Strano, MS ;

Dyke, CA ;

Usrey, ML ;

Barone, PW ;

Allen, MJ ;

Shan, HW ;

Kittrell, C ;

Hauge, RH ;

Tour, JM ;

Smalley, RE .

SCIENCE, 2003, 301 (5639) :1519-1522

[10] A Convergent Approach to Biocompatible Polyglycerol "Click" Dendrons for the Synthesis of Modular Core-Shell Architectures and Their Transport Behavior [J].

Wyszogrodzka, Monika ;

Haag, Rainer .

CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (30) :9202-9214

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