Synthesis, structure and luminescence of {Zn2Ln(OH)} (Ln = Eu, Gd, Tb) complexes with a triangular metal core

被引：18
作者：
Kiskin, Mikhail A. [1 ]
Varaksina, Evgenia A. [2 ,3 ,4 ]
Taydakov, Ilya V. [2 ,3 ]
Eremenko, Igor L. [1 ,3 ]
机构：
[1] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Leninsky Prosp 31, Moscow 119991, Russia
[2] Russian Acad Sci, PN Lebedev Phys Inst, Leninsky Prosp 53, Moscow 119991, Russia
[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilova St 28, Moscow 119991, Russia
[4] Moscow Inst Phys & Technol, Inst Sky Lane 9, Dolgoprudnyi 141700, Moscow Region, Russia
来源：
INORGANICA CHIMICA ACTA | 2018年 / 482卷
基金：
俄罗斯科学基金会;
关键词：
Zn-Ln complexes; Heterometallic; X-ray; Luminescence; Triplet state energy; LANTHANIDE(III) COMPLEXES; PHOTOPHYSICAL PROPERTIES; TERBIUM(III) COMPLEXES; CRYSTAL-STRUCTURE; QUANTUM YIELD; EUROPIUM; LIGANDS; CHEMISTRY; EMISSION; STATES;
D O I：
10.1016/j.ica.2018.05.037
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Heterometallic {Zn-Ln}-complexes [Zn(2)Ln(OH)(Piv)(4)(NO3)(2)(pyzphen)(2)], where Ln is Eu (1), Gd (2) or Tb (3), Piv-is an anion of pivalic acid and pyzphen is pyrazino[2,3-f][1,10] phenanthroline, were synthesized. Crystallographic cell parameters and XRPD study show the compounds to be isostructural. The crystal structure of 3 was determined by single crystal X-ray analysis. The complexes contained two pyzphen ligands coordinated by Zn ions. Inter-and intra-molecular interactions between aromatic fragments of pyzphen resulted in the formation of a stack structure. The triplet state energy of pyzphen in complex 2 is 22200 cm(-1). Analysis of the luminescence of 1 and 3 showed a low efficiency of ligand-to-metal energy transfer.
引用
收藏
页码：85 / 89
页数：5
相关论文
共 30 条
  • [1] Shape maps and polyhedral interconversion paths in transition metal chemistry[J]. Alvarez, S;Alemany, P;Casanova, D;Cirera, J;Llunell, M;Avnir, D. COORDINATION CHEMISTRY REVIEWS, 2005(17-18)
  • [2] [Anonymous], 1997, SMART CONTR SAINT IN
  • [3] Structural and photophysical properties of mononuclear and dinuclear lanthanide(III) complexes of multidentate podand ligands based on poly(pyrazolyl)borates[J]. Armaroli, N;Accorsi, G;Barigelletti, P;Couchman, SM;Fleming, JS;Harden, NC;Jeffery, JC;Mann, KLV;McCleverty, JA;Rees, LH;Starling, SR;Ward, MD. INORGANIC CHEMISTRY, 1999(25)
  • [4] Non-radiative deactivation of the excited states of europium, terbium and ytterbium complexes by proximate energy-matched OH, NH and CH oscillators: an improved luminescence method for establishing solution hydration states[J]. Beeby, A;Clarkson, IM;Dickins, RS;Faulkner, S;Parker, D;Royle, L;de Sousa, AS;Williams, JAG;Woods, M. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1999(03)
  • [5] Intriguing aspects of lanthanide luminescence[J]. Buenzli, Jean-Claude G.;Eliseeva, Svetlana V. CHEMICAL SCIENCE, 2013(05)
  • [6] Taking advantage of luminescent lanthanide ions[J]. Bünzli, JCG;Piguet, C. CHEMICAL SOCIETY REVIEWS, 2005(12)
  • [7] The rich stereochemistry of eight-vertex polyhedra: A continuous shape measures study[J]. Casanova, D;Llunell, M;Alemany, P;Alvarez, S. CHEMISTRY-A EUROPEAN JOURNAL, 2005(05)
  • [8] Luminescence properties of Ba2NaNb5O15 crystals activated with Sm3+, Eu3+, Tb3+ or Dy3+ ions[J]. Cavalli, Enrico;Belletti, Alessandro;Mahiou, Rachid;Boutinaud, Philippe. JOURNAL OF LUMINESCENCE, 2010(04)
  • [9] Lanthanide-based emitting materials in light-emitting diodes[J]. de Bettencourt-Dias, Ana. DALTON TRANSACTIONS, 2007(22)
  • [10] Recent developments in the field of supramolecular lanthanide luminescent sensors and self-assemblies[J]. dos Santos, Cidalia M. G.;Harte, Andrew J.;Quinn, Susan J.;Gunnlaugsson, Thorfinnur. COORDINATION CHEMISTRY REVIEWS, 2008(23-24)
123