Experimental Confirmation of the Low-Temperature Oxidation Scheme of Alkanes

被引：187

作者：

Battin-Leclerc, Frederique ^{[1
]}

Herbinet, Olivier ^{[1
]}

Glaude, Pierre-Alexandre ^{[1
]}

Fournet, Rene ^{[1
]}

Zhou, Zhongyue ^{[2
]}

Deng, Liulin ^{[2
]}

Guo, Huijun ^{[2
]}

Xie, Mingfeng ^{[2
]}

Qi, Fei ^{[2
]}

机构：

[1] Nancy Univ, CNRS, Lab React & Genie Procedes, ENSIC, F-54001 Nancy, France

[2] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 18期

基金：

欧洲研究理事会;

关键词：

hydroperoxides; mass spectrometry; molecular beams; oxidation; photoionization; N-HEPTANE; HYDROCARBONS; AUTOIGNITION; COMBUSTION; MIXTURES; PRESSURE; IGNITION; REACTOR; MODEL;

D O I：

10.1002/anie.200906850

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical equation presented) Intermediate detected: The design of internal combustion engines relies on a good understanding of the mechanism of the auto-ignition of hydrocarbons. A key assumption of this mechanism, which was commonly accepted but never proven, has now been experimentally demonstrated: the formation of ketohydroperoxides has been observed under conditions close to those actually observed before the auto-ignition. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3169 / 3172

页数：4

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