Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands

被引：176

作者：

Inagaki, Tomohiko ^{[1
]}

Phong, Le Thanh ^{[1
]}

Furuta, Akihiro ^{[1
]}

Ito, Jun-ichi ^{[1
]}

Nishiyama, Hisao ^{[1
]}

机构：

[1] Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 10期

基金：

日本学术振兴会;

关键词：

asymmetric catalysis; bisoxazoline ligands; cobalt; hydrosilylation; iron; FRIEDEL-CRAFTS ALKYLATION; C-2-SYMMETRIC TRIDENTATE BIS(OXAZOLINE); ENANTIOSELECTIVE BOROHYDRIDE REDUCTION; CARBONYL-COMPOUNDS; TRANSFER HYDROGENATION; CONJUGATE REDUCTION; HENRY REACTION; COMPLEXES; EFFICIENT; BIS(THIAZOLINE);

D O I：

10.1002/chem.200903118

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral bis(oxazolinylphenyl)amines proved to be efficient auxiliary ligands for iron and cobalt catalysts with high activity for asymmetric hydrosilylation of ketones and asymmetric conjugate hydrosilylation of enones.

引用

页码：3090 / 3096

页数：7

共 46 条

[21]

Leutenegger U., 1989, ANGEW CHEM, V101, P61

[22] Asymmetric Friedel-Crafts alkylation of electron-rich N-heterocycles with nitroalkenes catalyzed by diphenylamine-tethered bis(oxazoline) and bis(thiazoline) ZnII complexes [J].

Liu, Han ;

Lu, Shao-Feng ;

Xu, Jiaxi ;

Du, Da-Ming .

CHEMISTRY-AN ASIAN JOURNAL, 2008, 3 (07) :1111-1121

[23] Asymmetric friedel-crafts alkylation of methoxyfuran with nitroalkenes catalyzed by diphenylamine-tethered Bis(oxazoline)-Zn(II) complexes [J].

Liu, Han ;

Xu, Jiaxi ;

Du, Da-Ming .

ORGANIC LETTERS, 2007, 9 (23) :4725-4728

[24] Enantioselective Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by bifunctional tridentate bis(oxazoline)-Zn(II) complex [J].

Lu, SF ;

Du, DM ;

Xu, JX .

ORGANIC LETTERS, 2006, 8 (10) :2115-2118

[25] Facile synthesis of C2-symmetric tridentate bis(thiazoline) and bis(oxazoline) ligands and their application in the enantioselective Henry reaction [J].

Lu, SF ;

Du, DM ;

Zhang, SW ;

Xu, JX .

TETRAHEDRON-ASYMMETRY, 2004, 15 (21) :3433-3441

[26] Asymmetric Michael addition of nitroalkanes to nitroalkenes catalyzed by C2-symmetric tridentate bis(oxazoline) and bis(thiazoline) zinc complexes [J].

Lu, Shao-Feng ;

Du, Da-Ming ;

Xu, Jiaxi ;

Zhang, Shi-Wei .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (23) :7418-7419

[27] Application of tridentate bis(oxazoline) ligands in catalytic asymmetric Nozaki-Hiyama allylation and crotylation: An example of high enantioselection with a non-symmetric bis(oxazoline) ligand [J].

McManus, HA ;

Cozzi, PG ;

Guiry, PJ .

ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (4-5) :551-558

[28] Coupling of bulky, electron-deficient partners in aryl amination in the preparation of tridentate bis(oxazoline) ligands for asymmetric catalysis [J].

McManus, HA ;

Guiry, PJ .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (24) :8566-8573

[29] Recent developments in the application of oxazoline-containing ligands in asymmetric catalysis [J].

McManus, HA ;

Guiry, PJ .

CHEMICAL REVIEWS, 2004, 104 (09) :4151-4202

[30] Iron(II) Complexes for the Efficient Catalytic Asymmetric Transfer Hydrogenation of Ketones [J].

Meyer, Nils ;

Lough, Alan J. ;

Morris, Robert H. .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (22) :5605-5610

← 1 2 3 4 5 →