Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands

被引：176

作者：

Inagaki, Tomohiko ^{[1
]}

Phong, Le Thanh ^{[1
]}

Furuta, Akihiro ^{[1
]}

Ito, Jun-ichi ^{[1
]}

Nishiyama, Hisao ^{[1
]}

机构：

[1] Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 10期

基金：

日本学术振兴会;

关键词：

asymmetric catalysis; bisoxazoline ligands; cobalt; hydrosilylation; iron; FRIEDEL-CRAFTS ALKYLATION; C-2-SYMMETRIC TRIDENTATE BIS(OXAZOLINE); ENANTIOSELECTIVE BOROHYDRIDE REDUCTION; CARBONYL-COMPOUNDS; TRANSFER HYDROGENATION; CONJUGATE REDUCTION; HENRY REACTION; COMPLEXES; EFFICIENT; BIS(THIAZOLINE);

D O I：

10.1002/chem.200903118

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral bis(oxazolinylphenyl)amines proved to be efficient auxiliary ligands for iron and cobalt catalysts with high activity for asymmetric hydrosilylation of ketones and asymmetric conjugate hydrosilylation of enones.

引用

页码：3090 / 3096

页数：7

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