Synthesis of ionisable [2 x 2] grid-type metallo-arrays and reversible protonic modulation of the optical properties of the [Co4IIL4]8+ species

被引：111

作者：

Ruben, M

Lehn, JM

Vaughanc, G

机构：

[1] ISIS, F-67083 Strasbourg, France

[2] Forschungszentrum Karlsruhe, Inst Nanotechnol, D-76021 Karlsruhe, Germany

[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 12期

关键词：

D O I：

10.1039/b303922f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new bis-hydrazone based ligands A and B form ionisable [2 x 2] grid-type transition metal complexes whose properties may be modulated by multiple protonation/deprotonation as shown by the reversible change in optical properties of the [(Co4L4)-L-II](8+) complexes depending on their protonation state.

引用

页码：1338 / 1339

页数：2

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