Synthesis and characterization of metalorganic polymers of intrinsic microporosity based on iron(II) clathrochelate

被引：24
|
作者：
Alameddine, Bassam [1 ]
Shetty, Suchetha [1 ]
Baig, Noorullah [1 ]
Al-Mousawi, Saleh [2 ]
Al-Sagheer, Fakhreia [2 ]
机构：
[1] Gulf Univ Sci & Technol, Dept Math & Nat Sci, Mubarak Al Abdullah, Kuwait
[2] Univ Kuwait, Dept Chem, Kuwait, Kuwait
来源：
POLYMER | 2017年 / 122卷
关键词：
Polymers of intrinsic microporosity; Iron(II) clathrochelate; Polycondensation; Surface area; Adsorption isotherms; COVALENT ORGANIC FRAMEWORKS; POROUS AROMATIC FRAMEWORK; ENERGY-STORAGE; SURFACE-AREA; SOLID-STATE; MEMBRANES; GAS; CRYSTALLINE; ADSORPTION; SEPARATION;
D O I：
10.1016/j.polymer.2017.06.048
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Four Iron(II) clathrochelate derived polymers (P1-4) were synthesized under mild reaction conditions using iron(II) chloride with benzene-1,4-diboronic acid in presence of various vicinal dioxime moieties. The polymers were characterized by different instrumental analyses techniques and their structures were further confirmed by comparison of their respective synthesized prototypical monomers (M). Evaluation of P1-4 intrinsic microporosity was carried out by nitrogen adsorption measurements where polymer P4 reveals a Brunauer-Emmett-Teller (BET) surface area of 412 m(2)/g and average pore volume of 0.36 cm(3)/g. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：200 / 207
页数：8
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