Quinoneimido Complexes of a Metalloporphyrin: Isolation, X-ray Crystal Structures, and DFT Calculations

被引：2
|
作者：
Tsui, Wai-Man [1 ,2 ]
Huang, Jie-Sheng [1 ,2 ]
Tong, Glenna So Ming [1 ,2 ]
Kui, Steven C. F. [1 ,2 ]
Che, Chi-Ming [1 ,2 ]
Zhu, Nianyong [1 ,2 ]
机构：
[1] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Univ Hong Kong, Inst Mol Technol Drug Discovery & Synth, Open Lab Chem Biol, Hong Kong, Hong Kong, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2010年 / 5卷 / 04期
关键词：
density functional calculations; N ligands; porphyrins; quinoneimido complexes; ruthenium; ELECTRON-TRANSFER SERIES; DIOXORUTHENIUM(VI) PORPHYRINS; MOLECULAR-STRUCTURE; TRANSITION-METALS; LIGAND; REACTIVITY; OXIDATION; BONDS; RUTHENIUM(II); DERIVATIVES;
D O I：
10.1002/asia.200900666
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Terminal quinoneimido complexes [RuIV (por) (NQu)(X)] (X=OEt: 1, OH: 2) were formed from the reaction of [Ru VI(por)O2] with 2,6-dimethylaniline. The X-ray crystal structures of 1 feature Ru-N(quinoneimido) bond lengths of 1.787(7)-1.80(2). Reaction of 2 with N-phenyl-benzene-1,4-diamine afforded bis(quinoneimido) complex [Ru(por) (NQu) (NQu')]. DFT calculations on 3 and 4 revealed a significant effect of 'Ru doping' on the oligoaniline structure. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：759 / 763
页数：5
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