Pyrolysis of brewer's spent grain: Kinetic study and products identification

被引:66
作者
Borel, Lidja D. M. S. [1 ]
Lira, Taisa S. [2 ]
Ribeiro, Janio A. [3 ]
Ataide, Carlos H. [1 ]
Barrozo, Marcos A. S. [1 ]
机构
[1] Univ Fed Uberlandia, Sch Chem Engn, Uberlandia, MG, Brazil
[2] Univ Fed Espirito Santo, Dept Engn Technol, Vitoria, Brazil
[3] Univ Fed Mato Grosso, Inst Engn, Cuiaba, Brazil
关键词
Brewer's spent grain; Thermogravimetric analysis; Biomass; Pyrolysis; FLUIDIZED-BED REACTOR; BIO-OIL PRODUCTION; THERMOGRAVIMETRIC ANALYSIS; SUGARCANE BAGASSE; THERMOCHEMICAL CHARACTERIZATION; PY-GC/MS; THERMAL-DECOMPOSITION; SENSITIVITY-ANALYSIS; BIOMASS RESIDUES; MODEL;
D O I
10.1016/j.indcrop.2018.05.051
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
In this study, the physicochemical properties, the thermal degradation behavior and the products generated from pyrolysis of brewer's spent grain (BSG) were investigated to evaluate the potential of this agro-industrial residue for bio-oil production via pyrolysis. Thermogravimetric analyses were performed in a nitrogen atmosphere. The kinetic parameters were estimated by isoconversional methods and by independent parallel reactions model (IPR). The results showed that the BSG has a good potential for bio-oil production owing to its high volatile matter content and the high heating value. The kinetic behavior was successfully modeled by the IPR model. High added-value compounds were identified from analytical pyrolysis, which indicates that BSG can be a source of important raw materials for the chemical industry.
引用
收藏
页码:388 / 395
页数:8
相关论文
共 56 条
[1]  
Aliyu S, 2011, AFR J BIOTECHNOL, V10, P324
[2]   Analysis of reaction kinetics of carton packaging pyrolysis [J].
Alvarenga, L. M. ;
Xavier, T. P. ;
Barrozo, M. A. S. ;
Bacelos, M. S. ;
Lira, T. S. .
CHISA 2012, 2012, 42 :113-122
[3]   Determination of activation energy of pyrolysis of carton packaging wastes and its pure components using thermogravimetry [J].
Alvarenga, Larissa M. ;
Xavier, Thiago P. ;
Barrozo, Marcos Antonio S. ;
Bacelos, Marcelo S. ;
Lira, Taisa S. .
WASTE MANAGEMENT, 2016, 53 :68-75
[4]   Bio-oil production from rice husk fast pyrolysis in a conical spouted bed reactor [J].
Alvarez, Jon ;
Lopez, Gartzen ;
Amutio, Maider ;
Bilbao, Javier ;
Olazar, Martin .
FUEL, 2014, 128 :162-169
[5]   Fast pyrolysis of eucalyptus waste in a conical spouted bed reactor [J].
Amutio, Maider ;
Lopez, Gartzen ;
Alvarez, Jon ;
Olazar, Martin ;
Bilbao, Javier .
BIORESOURCE TECHNOLOGY, 2015, 194 :225-232
[6]   Characterization and product formation during the catalytic and non-catalytic pyrolysis of the green microalgae Chlamydomonas reinhardtii [J].
Andrade, L. A. ;
Batista, F. R. X. ;
Lira, T. S. ;
Barrozo, M. A. S. ;
Vieira, L. G. M. .
RENEWABLE ENERGY, 2018, 119 :731-740
[7]   Thermo-chemical behavior and product formation during pyrolysis of mango seed shell [J].
Andrade, L. A. ;
Barrozo, M. A. S. ;
Vieira, L. G. M. .
INDUSTRIAL CROPS AND PRODUCTS, 2016, 85 :174-180
[8]   Conventional and modified rotary dryer: Comparison of performance in fertilizer drying [J].
Arruda, E. B. ;
Facanha, J. M. F. ;
Pires, L. N. ;
Assis, A. J. ;
Barrozo, M. A. S. .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2009, 48 (09) :1414-1418
[9]  
Buffington J., 2014, ADV CHEM ENG SCI
[10]   Analytical pyrolysis of tobacco residue: Effect of temperature and inorganic additives [J].
Cardoso, C. R. ;
Ataide, C. H. .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2013, 99 :49-57