Reversible anion intercalation in a layered aromatic amine: a high-voltage host structure for organic batteries

被引:101
作者
Deunf, Elise [1 ]
Moreau, Philippe [1 ]
Quarez, Eric [1 ]
Guyomard, Dominique [1 ]
Dolhem, Franck [2 ,3 ]
Poizot, Philippe [1 ,4 ]
机构
[1] Univ Nantes, UMR CNRS 6502, Inst Mat Jean Rouxel IMN, 2 Rue Houssiniere,BP 32229, F-44322 Nantes 3, France
[2] Univ Picardie Jules Verne, UMR CNRS 7378, Lab Glycochim Antimicrobiens & Agroressources LG2, 33 Rue St Leu, F-80039 Amiens, France
[3] FR CNRS 3459, Reseau Stockage Eectrochim Energie RS2E, Paris, France
[4] Inst Univ France, 103 Bd St Michel, F-75005 Paris 5, France
关键词
RECHARGEABLE BATTERIES; RADICAL POLYMERS; ACTIVE MATERIAL; ELECTRODE; LITHIUM; CATHODE; GRAPHITE; PERFORMANCE; CAPACITY; BEHAVIOR;
D O I
10.1039/c6ta02356h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cation insertion reactions in inorganic host frameworks are well-established phenomena. Over the last 40 years, a myriad of examples have been documented, which have given rise to key applications such as for electrochemical storage devices. By contrast, materials able to reversibly insert anions into their host lattice are rare, and consist essentially of graphite intercalation compounds (GICs), thus limiting their potential use. Organic materials, conversely, if properly designed, could pave the way for future developments in anionic insertion electrochemistry, by virtue of the rational incorporation of p-type redox-active organic moieties. Here, we report the discovery of a p-type organic host lattice based on a simple crystallized aromatic diamine. The reversible anion insertion process relies on the electrochemical activity of neutral secondary amino groups incorporated into a robust terephthalate backbone. XRD, TEM and EELS studies reveal the attainment of a unique lamellar structure conducive to the oxidative insertion of anions (including the bulky TFSI-). In a dual-ion cell configuration using lithium as the negative electrode, this organic structure can react reversibly at high operating potential (< E > approximate to 3.22 V vs. Li+/Li) with good cycling performance even without carbon addition, hence generating further avenues for the development of organic batteries and more generally, the field of intercalation chemistry.
引用
收藏
页码:6131 / 6139
页数:9
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