Tuning the optical properties of the zirconium-UiO-66 metal-organic framework for photocatalytic degradation of methyl orange

被引：96
作者：
Pu, Shan [1 ]
Xu, Lei [1 ]
Sun, Lin [1 ]
Du, Hongbin [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 52卷
基金：
中国国家自然科学基金;
关键词：
MOFs; Zirconium; UiO-66; analogs; Photocatalysis; Degradation of methyl orange; CO2; REDUCTION; BLUE DYE; DECOLORIZATION;
D O I：
10.1016/j.inoche.2014.12.015
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new UiO-66-type zirconium metal organic framework material UiO-66(AN) was prepared by using chromophoric anthracene-9,10-dicarboxylic acid as linker. The large-sized conjugate pi-system in the ligand results in the bathochromic shift of the absorption peaks into the visible light region in the absorption spectrum of UiO-66(AN), compared to those of UiO-66 and analogs UiO-66(NA) made of terephthalate and naphthalene-1,4-dicarboxylic add, respectively. UiO-66(AN) was shown to be an efficient photocatalyst for degradation of methyl orange. Our finding shows promises for the development of more efficient MOFs as photocatalysts by using chromophoric conjugate ligands. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：50 / 52
页数：3
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