Electrocatalytic Oxidation of 5-(Hydroxymethyl)furfural Using High-Surface-Area Nickel Boride

被引：391

作者：

Barwe, Stefan ^{[1
]}

Weidner, Jonas ^{[1
]}

Cychy, Steffen ^{[2
]}

Morales, Dulce M. ^{[1
]}

Dieckhofer, Stefan ^{[1
]}

Hiltrop, Dennis ^{[2
]}

Masa, Justus ^{[1
]}

Muhler, Martin ^{[2
]}

Schuhmann, Wolfgang ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Fac Chem & Biochem, CES, Analyt Chem, Univ Str 150, D-44780 Bochum, Germany

[2] Ruhr Univ Bochum, Fac Chem & Biochem, Lab Ind Chem, Univ Str 150, D-44780 Bochum, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 35期

关键词：

ATR-IR; electrocatalysis; electrosynthesis; HMF oxidation; nickel boride; SELECTIVE AEROBIC OXIDATION; 2,5-FURANDICARBOXYLIC ACID; MILD CONDITIONS; ELECTROCHEMICAL OXIDATION; CATALYZED OXIDATION; HYDROGEN-PRODUCTION; WATER; HMF; NANOPARTICLES; NANOCATALYST;

D O I：

10.1002/anie.201806298

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The electrochemical oxidation of the biorefinery product 5-(hydroxymethyl)furfural (HMF) to 2,5-furandicarboxylic acid (FDCA), an important platform chemical for the polymer industry, is receiving increasing interest. FDCA-based polymers such as polyethylene 2,5-furandicarboxylate (PEF) are sustainable candidates for replacing polyethylene terephthalate (PET). Herein, we report the highly efficient electrocatalytic oxidation of HMF to FDCA, using Ni foam modified with high-surface-area nickel boride (NixB) as the electrode. Constant potential electrolysis in combination with HPLC revealed a high faradaic efficiency of close to 100% towards the production of FDCA with a yield of 98.5%. Operando electrochemistry coupled to ATR-IR spectroscopy indicated that HMF is oxidized preferentially via 5-hydroxymethyl-2-furancarboxylic acid rather than via 2,5-diformylfuran, which is in agreement with HPLC results. This study not only reports a low-cost active electrocatalyst material for the electrochemical oxidation of HMF to FDCA, but additionally provides insight into the reaction pathway.

引用

页码：11460 / 11464

页数：5

共 39 条

[1] Influence of Temperature and Electrolyte Concentration on the Structure and Catalytic Oxygen Evolution Activity of Nickel-Iron Layered Double Hydroxide [J].

Andronescu, Corina ;

Seisel, Sabine ;

Wilde, Patrick ;

Barwe, Stefan ;

Masa, Justus ;

Chen, Yen-Ting ;

Ventosa, Edgar ;

Schuhmann, Wolfgang .

CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (52) :13773-13777

[2] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited [J].

Bozell, Joseph J. ;

Petersen, Gene R. .

GREEN CHEMISTRY, 2010, 12 (04) :539-554

[3] Gold Nanoclusters Confined in a Supercage of Y Zeolite for Aerobic Oxidation of HMF under Mild Conditions [J].

Cai, Jiaying ;

Ma, Hong ;

Zhang, Junjie ;

Song, Qi ;

Du, Zhongtian ;

Huang, Yizheng ;

Xu, Jie .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (42) :14215-14223

[4]

Cha HG, 2015, NAT CHEM, V7, P328, DOI [10.1038/NCHEM.2194, 10.1038/nchem.2194]

[5] Electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid on supported Au and Pd bimetallic nanoparticles [J].

Chadderdon, David J. ;

Xin, Le ;

Qi, Ji ;

Qiu, Yang ;

Krishna, Phani ;

More, Karren L. ;

Li, Wenzhen .

GREEN CHEMISTRY, 2014, 16 (08) :3778-3786

[6] Oxidation of 5-hydroxymethylfurfural over supported Pt, Pd and Au catalysts [J].

Davis, Sara E. ;

Houk, Levi R. ;

Tamargo, Erin C. ;

Datye, Abhaya K. ;

Davis, Robert J. .

CATALYSIS TODAY, 2011, 160 (01) :55-60

[7] Replacing fossil based PET with biobased PEF; process analysis, energy and GHG balance [J].

Eerhart, A. J. J. E. ;

Faaij, A. P. C. ;

Patel, M. K. .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (04) :6407-6422

[8] KINETICS AND MECHANISM OF OXIDATION OF AMINES AND ALCOHOLS AT OXIDE-COVERED NICKEL, SILVER, COPPER, AND COBALT ELECTRODES [J].

FLEISCHM.M ;

PLETCHER, D ;

KORINEK, K .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1972, (10) :1396-&

[9] SYNTHETICALLY USEFUL REACTIONS WITH METAL BORIDE AND ALUMINIDE CATALYSTS [J].

GANEM, B ;

OSBY, JO .

CHEMICAL REVIEWS, 1986, 86 (05) :763-780

[10] THE ELECTROCHEMICAL OXIDATION OF 5-HYDROXYMETHYLFURFURAL WITH THE NICKEL-OXIDE HYDROXIDE ELECTRODE [J].

GRABOWSKI, G ;

LEWKOWSKI, J ;

SKOWRONSKI, R .

ELECTROCHIMICA ACTA, 1991, 36 (13) :1995-1995

← 1 2 3 4 →