Photoelectrochemical decomposition of water utilizing monolithic tandem cells

被引:29
作者
Kocha, SS [1 ]
Montgomery, D [1 ]
Peterson, MW [1 ]
Turner, JA [1 ]
机构
[1] Natl Renewable Energy Lab, Golden, CO 80401 USA
关键词
decomposition; monolithic tandem cells;
D O I
10.1016/S0927-0248(97)00245-6
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Photovoltaic tandem cells consisting of a gallium indium phosphide (GaInP2) homojunction grown epitaxially upon a gallium arsenide (GaAs) homojunction, with a GaAs tunnel-diode interconnection were utilized to photoelectrochemically decompose water in a 1 M sulfuric acid electrolyte solution. Using a sol-gel process, a platinum colloid in water was used to modify the illuminated front surface of the device to catalyze the water decomposition process. A unique feature of this device is that the hydrogen and oxygen are co-evolved from the illuminated surface. The exact mechanism of the water decomposition process is not fully understood at this time. (C) 1998 Published by Elsevier Science B.V. All rights reserved.
引用
收藏
页码:389 / 397
页数:9
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