Transfer thermodynamic functions ΔGto, ΔHto and TΔSto of cis- and trans-[CoCl2(en)2]+ isomers in aqueous mixtures of methanol, tert-butyl alcohol and acetonitrile

被引：0

作者：

Vollárová, O ^{[1
]}

Benko, J ^{[1
]}

机构：

[1] Comenius Univ, Dept Phys Chem, Bratislava 84215, Slovakia

来源：

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS | 2000年 / 65卷 / 09期

关键词：

complex ions; solvation; transfer thermodynamic functions; partial molar volumes; thermodynamics; cobalt; solubility;

D O I：

10.1135/cccc20001455

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The solubility, partial molar volume and standard integral molar enthalpy of solution of cis-and trans-[CoCl2(en)(2)]Cl in water, aqueous methanol, aqueous tert-butyl alcohol and aqueous acetonitrile are reported. The transfer functions DeltaG(t)(0), DeltaH(t)(0) and T DeltaS(t)(0) as well as partial molar volumes are used to obtain information on the solute-solvent interactions. Results obtained are discussed in terms of differences in the surface charge distribution in isomeric coordination species.

引用

页码：1455 / 1463

页数：9