Chiral diiminophosphoranes: a new class of ligands for enantioselective transition metal catalysis

被引:65
|
作者
Reetz, MT [1 ]
Bohres, E [1 ]
Goddard, R [1 ]
机构
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
关键词
D O I
10.1039/a709023d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral diamines such as (1R,2R)-1,2-diaminocyclohexane or R-2,2'-diamino-1,1'-binaphthalene can be converted into the corresponding diimino(triphenyl)phosphoranes, which serve as C-2-symmetric ligands for enantioselective transition metal catalyzed reactions such as copper-mediated cyclopropanations.
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页码:935 / 936
页数:2
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