Chiral diiminophosphoranes: a new class of ligands for enantioselective transition metal catalysis

被引：65

作者：

Reetz, MT ^{[1
]}

Bohres, E ^{[1
]}

Goddard, R ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 08期

关键词：

D O I：

10.1039/a709023d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral diamines such as (1R,2R)-1,2-diaminocyclohexane or R-2,2'-diamino-1,1'-binaphthalene can be converted into the corresponding diimino(triphenyl)phosphoranes, which serve as C-2-symmetric ligands for enantioselective transition metal catalyzed reactions such as copper-mediated cyclopropanations.

引用

页码：935 / 936

页数：2

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