A-Type regioregular oligothiophenes: Synthesis and second-order NLO properties

被引：45

作者：

Zrig, Samia

Koeckelberghs, Guy

Verbiest, Thierry

Andrioletti, Bruno

Rose, Eric

Persoons, Andre

Asselberghs, Inge

Clays, Koen

机构：

[1] Univ Paris 06, CNRS, UMR 7611, Lab Chim Organ,Inst Chim Mol FR 2769, F-75252 Paris 05, France

[2] Katholieke Univ Leuven, Dept Chem, Lab Mol Elect & Photon, B-3001 Heverlee, Belgium

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 15期

关键词：

D O I：

10.1021/jo070888a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of a new series of Lambda-type, D-Pi-A regioregular oligothiophenes is described. The simultaneous presence of the chiral centers and the Lambda-type structure disfavored the formation of centro-symmetrical dimeric assemblies. Hence, enhanced first hyperpolarizabilities beta(HRS) were measured in comparison with those of the corresponding monomers.

引用

收藏

页码：5855 / 5858

页数：4

相关论文

共 30 条

[1] Synthesis and relative thermal stabilities of diphenylamino- vs piperidinyl-substituted bithiophene chromophores for nonlinear optical materials [J].

Bedworth, PV ;

Cai, YM ;

Jen, A ;

Marder, SR .

JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (06) :2242-2246

[2] Molecular salts with diquat-based electron acceptors for nonlinear optics [J].

Coe, BJ ;

Harris, JA ;

Brunschwig, BS ;

Garín, J ;

Orduna, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) :3284-3285

[3] Novel chiral bis-dipolar 6,6'-disubstituted binaphthol derivatives for second-order nonlinear optics. Synthesis and linear and nonlinear optical properties [J].

Deussen, HJ ;

Hendrickx, E ;

Boutton, C ;

Krog, D ;

Clays, K ;

Bechgaard, K ;

Persoons, A ;

Bjornholm, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (29) :6841-6852

[4]

Hartwig J. F., 1995, TETRAHEDRON LETT, V36, P3609

[5] RELATIONSHIP BETWEEN OPTICAL SECOND HARMONIC GENERATION + ELECTRO-OPTIC EFFECT IN MOLECULAR CRYSTAL HEXAMINE [J].

HEILMEIER, GH ;

OCKMAN, N ;

BRAUNSTEIN, R ;

KRAMER, DA .

APPLIED PHYSICS LETTERS, 1964, 5 (11) :229-&

[6] Hyper-Rayleigh Scattering in isotropic solution [J].

Hendrickx, E ;

Clays, K ;

Persoons, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (10) :675-683

[7]

Heyde C, 2000, EUR J ORG CHEM, V2000, P3273

[8] About supramolecular assemblies of π-conjugated systems [J].

Hoeben, FJM ;

Jonkheijm, P ;

Meijer, EW ;

Schenning, APHJ .

CHEMICAL REVIEWS, 2005, 105 (04) :1491-1546

[9] DESIGN AND CONSTRUCTION OF MOLECULAR ASSEMBLIES WITH LARGE 2ND-ORDER OPTICAL NONLINEARITIES - QUANTUM-CHEMICAL ASPECTS [J].

KANIS, DR ;

RATNER, MA ;

MARKS, TJ .

CHEMICAL REVIEWS, 1994, 94 (01) :195-242

[10]

KINBINGER AFM, 2000, J AM CHEM SOC, V122, P1820