Recent advances in the asymmetric hydrosilylation of ketones, imines and electrophilic double bonds

被引：238
作者：
Riant, O [1 ]
Mostefaï, N [1 ]
Courmarcel, J [1 ]
机构：
[1] Catholic Univ Louvain, Lab Chim Organ & Med, B-1348 Louvain, Belgium
来源：
SYNTHESIS-STUTTGART | 2004年 / 18期
关键词：
asymmetric catalysis; asymmetric hydrosilylation; chiral ligands; rhodium; titanium; zinc; conjugate addition; reduction;
D O I：
10.1055/s-2004-834932
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This literature review focuses on the recent advances in the asymmetric hydrosilylation of ketones and imines. New catalyst systems based on various transition metals, such as rhodium, titanium, zinc, copper and tin, combined with classical or new ligand structures, are presented. These systems lead to very effective and selective protocols for the reduction of prochiral ketones, imines and electrophilic double bonds.
引用
收藏
页码：2943 / 2958
页数：16
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