Highly efficient Rh(I)/tris-H8-binaphthyl monophosphite catalysts for hydroformylation of dicyclopentadiene to dialdehydes

被引：6
作者：
Tian, Mi [1 ,2 ]
Li, Haifeng [1 ]
Wang, Lailai [1 ,3 ]
机构：
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Gansu, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Guangzhou Lee & Man Technol Co Ltd, Guangzhou 511458, Guangdong, Peoples R China
来源：
CHINESE JOURNAL OF CATALYSIS | 2018年 / 39卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Hydroformylation; Dicyclopentadiene; Monophosphite; Dialdehyde; Homogeneous catalysis; CHIRAL PHOSPHITE LIGANDS; ASYMMETRIC CONJUGATE ADDITION; CYCLIC ENONES; ALKENES; DIETHYLZINC; TRIPHENYLPHOSPHINE; PERFORMANCE; OLEFINS; SYSTEM;
D O I：
10.1016/S1872-2067(18)63098-0
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Novel catalytic systems for the Rh-catalyzed hydroformylation of dicyclopentadiene have been developed using tris-H-8-binaphthyl monophosphite as ligands containing different ester substituents at the 2'-binaphthyl position (OCOMe, OCOPh, OCOAdamantyl and OCOPhCI). The catalysts exhibited high activity (S/C = 4000, TON = 3286) with good to excellent selectivity towards dialdehydes. Remarkably, the Rh(I) complex bearing the ligands with chlorophenyl ester substituents led to 99.9% conversion and 98.7% selectivity for dialdehydes under relatively mild conditions (6 MPa, 120 degrees C). (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：1646 / 1652
页数：7
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