Conducting metal dithiolene complexes: Structural and electronic properties

被引：449
作者：
Kato, R [1 ]
机构：
[1] RIKEN, Inst Phys & Chem Res, Condensed Mol Mat Lab, Wako, Saitama 3510198, Japan
来源：
CHEMICAL REVIEWS | 2004年 / 104卷 / 11期
关键词：
D O I：
10.1021/cr030655t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
From the solid foundation of the two-band systems concept, a unifying picture is given of the very large effort on conducting metal dithiolene complexes where the fascinating interplay of the HOMO and LUMO orbitals within complexes where the HOMO-LUMO level splitting is small has yet to reach its full potential. Concepts such as orbital degree of freedom, multisheet Fermi surface, solid crossing column structures, and spanning overlap are formulated.
引用
收藏
页码：5319 / 5346
页数：28
相关论文
共 193 条
[101]   M(dmit)(2) and M(dmise)(2)(M=Ni,Pd) compounds with one-, two- and three-dimensional metallic bands [J].
Kobayashi, A ;
Sato, A ;
Naito, T ;
Kobayashi, H .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1996, 284 :85-96
[102]  
KOBAYASHI A, 1997, HDB ORGANIC CONDUCTI, V1, P249
[103]   MULTIDIMENSIONAL MOLECULAR-METALS WITH PI-ACCEPTOR M(DMIT)2 AND ANALOGOUS MOLECULES [J].
KOBAYASHI, H ;
KATO, R ;
KOBAYASHI, A .
SYNTHETIC METALS, 1991, 42 (03) :2495-2498
[104]   THE CRYSTAL-STRUCTURE OF [BEDT-TTF] [NI(DMIT)2] - A NEW ROUTE TO DESIGN OF ORGANIC CONDUCTORS [J].
KOBAYASHI, H ;
KATO, R ;
KOBAYASHI, A ;
SASAKI, Y .
CHEMISTRY LETTERS, 1985, (02) :191-194
[105]   NEW MOLECULAR SUPERCONDUCTOR, [ME2ET2N][PD(DMIT)2]2 [J].
KOBAYASHI, H ;
BUN, K ;
NAITO, T ;
KATO, R ;
KOBAYASHI, A .
CHEMISTRY LETTERS, 1992, (10) :1909-1912
[106]   THE CRYSTAL AND ELECTRONIC-STRUCTURES OF A NEW MOLECULAR CONDUCTOR, (TMTSF) [NI(DMIT)2] [J].
KOBAYASHI, H ;
KATO, R ;
KOBAYASHI, A ;
SASAKI, Y .
CHEMISTRY LETTERS, 1985, (04) :535-538
[107]   Origin of superconductivity in 2D-organic compounds and high-Tc cuprates [J].
Kondo, H ;
Moriya, T .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1999, 68 (10) :3170-3173
[108]  
KOTOV AI, 1991, SYNTHETIC MET, V42, P2355, DOI 10.1016/0379-6779(91)91380-S
[109]   THE CONDUCTIVITY AND BAND-STRUCTURE OF SOME SYNTHETIC SEMICONDUCTORS BASED ON NI(DMIT)2, PD(DMIT)2, PT(DMIT)2 [J].
KRAMER, GJ ;
JOL, JC ;
BROM, HB ;
GROENEVELD, LR ;
REEDIJK, J .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1988, 21 (25) :4591-4601
[110]  
Kushch LA, 1996, J PHYS I, V6, P1555, DOI 10.1051/jp1:1996173
6789101112131415