Catalytic oxidation of glycerol to tartronic acid over Au/HY catalyst under mild conditions

被引：48
作者：
Cai, Jiaying [1 ,2 ]
Ma, Hong [1 ]
Zhang, Junjie [1 ,2 ]
Du, Zhongtian [1 ]
Huang, Yizheng [1 ]
Gao, Jin [1 ]
Xu, Jie [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
来源：
CHINESE JOURNAL OF CATALYSIS | 2014年 / 35卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Catalytic oxidation; Glycerol; Gold; Tartronic acid; LIQUID-PHASE OXIDATION; AU; CHEMISTRY; BEHAVIOR; OXYGEN;
D O I：
10.1016/S1872-2067(14)60132-7
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Gold nanoclusters or nanoparticles on various supports (CeO2, activated carbon, HY, REY, and NaY) were investigated for glycerol oxidation in the aqueous phase under mild conditions. Compared with other catalysts, Au/HY showed remarkable catalytic performance in forming dicarboxylic acid (tartronic acid) over the monocarboxylic acid (glyceric acid) or the C-C cleavage product (oxalic acid). Au/HY achieved 98% conversion of glycerol and 80% yield of tartronic acid at 60 degrees C under 0.3 MPa O-2. Further characterization showed that the small size of Au clusters is the key factor for the high oxidation performance. In situ Fourier transform infrared spectroscopy revealed that glycerol was first transformed to glyceric acid, and then glyceric acid was directly oxidized to tartronic acid. (C) 2014, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：1653 / 1660
页数：8
相关论文
共 26 条
  • [1] Biodiesel production from crude Jatropha curcas L. seed oil with a high content of free fatty acids
    Berchmans, Hanny Johanes
    Hirata, Shizuko
    [J]. BIORESOURCE TECHNOLOGY, 2008, 99 (06) : 1716 - 1721
  • [2] Biesiada A, 2011, ECOL CHEM ENG A, V18, P9
  • [3] Feedstocks for the future: Renewables in green chemistry
    Bozell, Joseph J.
    [J]. CLEAN-SOIL AIR WATER, 2008, 36 (08) : 633 - 633
  • [4] Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "Top 10" revisited
    Bozell, Joseph J.
    Petersen, Gene R.
    [J]. GREEN CHEMISTRY, 2010, 12 (04) : 539 - 554
  • [5] Gold Nanoclusters Confined in a Supercage of Y Zeolite for Aerobic Oxidation of HMF under Mild Conditions
    Cai, Jiaying
    Ma, Hong
    Zhang, Junjie
    Song, Qi
    Du, Zhongtian
    Huang, Yizheng
    Xu, Jie
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (42) : 14215 - 14223
  • [6] Tartronates: A new generation of drugs affecting bone metabolism
    Caselli, G
    Mantovanini, M
    Gandolfi, CA
    Allegretti, M
    Fiorentino, S
    Pellegrini, L
    Melillo, G
    Bertini, R
    Sabbatini, W
    Anacardio, R
    Clavenna, G
    Sciortino, G
    Teti, A
    [J]. JOURNAL OF BONE AND MINERAL RESEARCH, 1997, 12 (06) : 972 - 981
  • [7] HYDROGENOLYSIS OF SORBITOL
    CLARK, IT
    [J]. INDUSTRIAL AND ENGINEERING CHEMISTRY, 1958, 50 (08): : 1125 - 1126
  • [8] Investigation on the behaviour of Pt(0)/carbon and Pt(0),Au(0)/carbon catalysts employed in the oxidation of glycerol with molecular oxygen in water
    Dimitratos, N.
    Messi, C.
    Porta, F.
    Prati, L.
    Villa, A.
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 256 (1-2) : 21 - 28
  • [9] Effect of particle size on monometallic and bimetallic (Au,Pd)/C on the liquid phase oxidation of glycerol
    Dimitratos, N
    Lopez-Sanchez, JA
    Lennon, D
    Porta, F
    Prati, L
    Villa, A
    [J]. CATALYSIS LETTERS, 2006, 108 (3-4) : 147 - 153
  • [10] Au, Pd (mono and bimetallic) catalysts supported on graphite using the immobilisation method - Synthesis and catalytic testing for liquid phase oxidation of glycerol
    Dimitratos, N
    Porta, F
    Prati, L
    [J]. APPLIED CATALYSIS A-GENERAL, 2005, 291 (1-2) : 210 - 214
123