Zirconia Sulfuric Acid: An Efficient Heterogeneous Catalyst for the One-Pot Synthesis of 3,4-Dihydropyrimidinones Under Solvent-Free Conditions

被引：45

作者：

Hosseini, Maliheh M. ^{[1
]}

Kolvari, Eskandar ^{[1
]}

Koukabi, Nadiya ^{[1
]}

Ziyaei, Maryam ^{[1
]}

Zolfigol, Mohammad Ali ^{[2
]}

机构：

[1] Semnan Univ, Dept Chem, Semnan, Iran

[2] Bu Ali Sina Univ, Fac Chem, Hamadan, Iran

来源：

CATALYSIS LETTERS | 2016年 / 146卷 / 06期

关键词：

Zirconia sulfuric acid; Solid acid catalyst; Biginelli; 3,4-Dihydropyrimidinones; Recyclability; SURFACTANT-COMBINED CATALYST; BIGINELLI REACTION; SULFONIC-ACID; NATURAL SUPPORT; DIHYDROPYRIMIDINONES; DIHYDROPYRIDINES; IMMOBILIZATION; ESTERIFICATION; CONDENSATION; DERIVATIVES;

D O I：

10.1007/s10562-016-1723-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this article, zirconia sulfuric acid (ZrSA) has been synthesized from the reaction of ZrO2 with chlorosulfonic acid. It was characterized by (FT-IR, XRD, TGA, SEM, EDS, BET, BJH, ICP and pH analysis). This catalyst was employed for the synthesis of 3,4-dihydropyrimidinones via cyclocondensation of beta-ketoester, aromatic aldehydes and urea/thiourea under solvent-free conditions. Main advantages of the catalyst were non toxic nature, high stability and reusability. .

引用

收藏

页码：1040 / 1049

页数：10

相关论文

共 56 条

[21] A catalytic method for synthesis of Biginelli-type 3,4-dihydropyrimidin-2 (1H)-one using 12-tungstophosphoric acid [J].

Heravi, MM ;

Derikvand, F ;

Bamoharram, FF .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 242 (1-2) :173-175

[22] Unprecedented catalytic three component one-pot condensation reaction: An efficient synthesis of 5-alkoxycarbonyl-4-aryl-3,4-dihydropyrimidin-2(1H)-ones [J].

Hu, EH ;

Sidler, DR ;

Dolling, UH .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (10) :3454-3457

[23] Porous zirconia: A new support material for enzyme immobilization [J].

Huckel, M ;

Wirth, HJ ;

Hearn, MTW .

JOURNAL OF BIOCHEMICAL AND BIOPHYSICAL METHODS, 1996, 31 (3-4) :165-179

[24] Perlite: an inexpensive natural support for heterogenization of HBF4 [J].

Kolvari, Eskandar ;

Koukabi, Nadiya ;

Hosseini, Maliheh M. ;

Khandani, Zeinab .

RSC ADVANCES, 2015, 5 (46) :36828-36836

[25] Perlite: A cheap natural support for immobilization of sulfonic acid as a heterogeneous solid acid catalyst for the heterocyclic multicomponent reaction [J].

Kolvari, Eskandar ;

Koukabi, Nadia ;

Hosseini, Maliheh M. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2015, 397 :68-75

[26] A Magnetic Particle-Supported Sulfonic Acid Catalyst: Tuning Catalytic Activity between Homogeneous and Heterogeneous Catalysis [J].

Koukabi, Nadiya ;

Kolvari, Eskandar ;

Zolfigol, Mohammad Ali ;

Khazaei, Ardeshir ;

Shaghasemi, Behzad Shirmardi ;

Fasahati, Behzad .

ADVANCED SYNTHESIS & CATALYSIS, 2012, 354 (10) :2001-2008

[27] An efficient bakers' yeast catalyzed synthesis of 3,4-dihydropyrimidin-2-(1 H)-ones [J].

Kumar, Atul ;

Maurya, Ram Awatar .

TETRAHEDRON LETTERS, 2007, 48 (26) :4569-4571

[28] Complementarity of heterogeneous and homogeneous catalysis for oleic acid esterification with trimethylolpropane over ion-exchange resins [J].

Kuzminska, Maryna ;

Backov, Renal ;

Gaigneaux, Eric M. .

CATALYSIS COMMUNICATIONS, 2015, 59 :222-225

[29] Immobilizing heteropolyacids on zirconia-modified silica as catalysts for oleochemistry transesterification and esterification reactions [J].

Kuzminska, Maryna ;

Kovalchuk, Tetyana V. ;

Backov, Renal ;

Gaigneaux, Eric M. .

JOURNAL OF CATALYSIS, 2014, 320 :1-8

[30] TGA/FT-IR studies of the deactivation of sulfated zirconia catalysts [J].

Li, BH ;

Gonzalez, RD .

APPLIED CATALYSIS A-GENERAL, 1997, 165 (1-2) :291-300

← 1 2 3 4 5 6 →