Synthesis of perhydroisoquinoline derivatives mediated by (eta(6)-arene)Cr(CO)(3) complexes

被引：7
|
作者：
Yeh, MCP
Chuang, CN
Yiu, CH
机构：
[1] Department of Chemistry, National Taiwan Normal University, Taipei 117, 88, Ding-Jou Road
来源：
TETRAHEDRON LETTERS | 1997年 / 38卷 / 42期
关键词：
D O I：
10.1016/S0040-4039(97)01731-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Reaction of lithium hexamethyldisilazide (LHMDS) with (eta(6)-arene)Cr(CO)(3) complexes bearing a beta-alaninenitrile moiety gives tetrahydroisoquinoline derivatives as the major products after oxidation of the reaction intermediate, whereas protonation of the reaction intermediates produces hexahydroisoquinoline as the major products. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：7387 / 7390
页数：4
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