A pillared layer MOF with anion-tunable magnetic properties and photochemical [2+2] cycloaddition

被引:126
作者
Wang, Xin-Yi [1 ]
Wang, Zhe-Ming [1 ]
Gao, Song [1 ]
机构
[1] Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
关键词
METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; SINGLE-CRYSTAL; COORDINATION; ASSEMBLIES; CHANNELS; SORPTION; POLYMER; FORMATE; SOLIDS;
D O I
10.1039/b616516h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A magnetic MOF with two distinct functions was prepared and characterized: [2 + 2] photodimerization and antiferromagnetism with a well-pronounced anion-tunable spin-flop transition below 2.5 K were both observed.
引用
收藏
页码:1127 / 1129
页数:3
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