Transmitted light relaxation and microstructure evolution of ferrofluids under gradient magnetic fields

Using light transmission experiments and optical microscope observations with a longitudinal gradient magnetic field configuration, the relationship between the behavior of the transmitted light relaxation and the microstructure evolution of ionic ferrofluids in the central region of an axisymmetric field is investigated. Under a low-gradient magnetic field, there are two types of relaxation process. When a field is applied, the transmitted light intensity decreases to a minimum within a time on the order of 10(1)-10(2) s. It is then gradually restored, approaching its initial value within a time on the order of 10(2) s. This is type I relaxation, which corresponds to the formation of magnetic columns. After the transmission reaches this value, it either increases or decreases slowly, stabilizing within a time on the order of 10(3) s, according to the direction of the field gradient. This is a type II relaxation, which results from the shadowing effect, corresponding to the motion of the magnetic columns under the application of a gradient force. Under a magnetic field with a centripetal high-gradient (magnetic materials subjected to a force pointing toward the center of the axisymmetric field), the transmitted light intensity decreases monotonously and more slowly than that under a low-gradient field. Magnetic transport and separation resulted from magnetophoresis under high-gradient fields, changing the formation dynamics of the local columns and influencing the final state of the column system. (C) 2014 Elsevier B.V. All rights reserved.