Infrared spectroscopy and Raman spectroscopy of cyclodextrin derivatives and their ferrocene inclusion complexes

被引：27

作者：

Heise, H. M. ^{[1
]}

Kuckuk, R. ^{[2
]}

Bereck, A. ^{[2
]}

Riegel, D. ^{[2
]}

机构：

[1] Tech Univ Dortmund, Leibniz Inst Analyt Wissensch ISAS eV, D-44139 Dortmund, Germany

[2] Berg Univ Wuppertal, D-42097 Wuppertal, Germany

来源：

VIBRATIONAL SPECTROSCOPY | 2010年 / 53卷 / 01期

关键词：

beta-Cyclodextrin derivatives; Ferrocene inclusion complex; Infrared spectroscopy; Raman spectroscopy; BETA-CYCLODEXTRIN;

D O I：

10.1016/j.vibspec.2010.01.012

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Cyclodextrins (CD) are cyclic oligosaccharides that are composed of five or more alpha-D-glucopyranoside units arranged to form molecular cavities with beta-cyclodextrin consisting of seven anhydroglucose units. The inclusion of ferrocene as a guest molecule in a beta-cyclodextrin derivative monomer (monochlorotriazinyl-beta-cyclodextrin) and in a derivative bound to cotton fabrics has been studied by infrared spectroscopy and Raman spectroscopy. The stability of the inclusion complex could be proven, although ferrocene itself shows a rather high sublimation pressure at room temperature. Raman spectroscopy delivers more significant and straight-forward structural information than the much less pronounced infrared spectral changes of the inclusion complex when compared to the spectra of water-loaded cyclodextrin cavities. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：19 / 23

页数：5

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