Unique anisotropic optical properties of a highly stable metal-organic framework based on trinuclear iron(III) secondary building units linked by tetracarboxylic linkers with an anthracene core

被引：16

作者：

Vinogradov, A. V. ^{[1
]}

Milichko, V. A. ^{[1
]}

Zaake-Hertling, H. ^{[2
]}

Aleksovska, A. ^{[2
]}

Gruschinski, S. ^{[2
]}

Schmorl, S. ^{[2
]}

Kersting, B. ^{[2
]}

Zolnhofer, E. M. ^{[3
]}

Sutter, J. ^{[3
]}

Meyer, K. ^{[3
]}

Lnnecke, P. ^{[2
]}

Hey-Hawkins, E. ^{[2
]}

机构：

[1] ITMO Univ, St Petersburg 197101, Russia

[2] Univ Leipzig, Fac Chem & Mineral, Inst Inorgan Chem, D-04103 Leipzig, Germany

[3] Univ Erlangen Nurnberg, Dept Chem & Pharm, Inorgan Chem, D-91058 Erlangen, Germany

来源：

DALTON TRANSACTIONS | 2016年 / 45卷 / 17期

基金：

俄罗斯基础研究基金会;

关键词：

LUMINESCENCE PROPERTIES; COORDINATION POLYMER; BIREFRINGENCE; LEAD(II); MOF;

D O I：

10.1039/c6dt00390g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A highly stable metal-organic framework, [{Fe-3(ACTBA)(2)}X center dot 6DEF](n) (1; X = monoanion), based on trinuclear iron(III) secondary building units connected by tetracarboxylates with an anthracene core, 2,6,9,10-tetrakis(p-carboxylatophenyl) anthracene (ACTBA), is reported. Depending on the direction of light polarisation, crystals of 1 exhibit anisotropic optical properties with birefringence Delta n = 0.3 (lambda = 590 nm).

引用

页码：7244 / 7249

页数：6

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