Amine adducts of titanium tetraalkoxides

被引：40
作者：
Fric, H [1 ]
Schubert, U [1 ]
机构：
[1] Vienna Univ Technol, Inst Mat Chem, A-1060 Vienna, Austria
来源：
NEW JOURNAL OF CHEMISTRY | 2005年 / 29卷 / 01期
关键词：
D O I：
10.1039/b411688g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The crystalline compounds Ti-2((OPr)-Pr-i)(8)(NH2Pr)(2), Ti-2((OPr)-Pr-i)(6)(OEt)(2)[NH2(CH2)(3)Si((OPr)-Pr-i)(3)](2) and Ti-2 ((OPr)-Pr-i)(8)[NH2(CH2)(6)NH2] were obtained by reaction of Ti((OPr)-Pr-i)(4) with the corresponding amines. The molecular structures of the amine adducts are centrosymmetric dimers in which the titanium atoms are bridged by two OR groups. The amines are coordinated axially to the Ti-2(mu-OR)(2) ring and hydrogen-bonded to a neighboring propoxy ligand. In the case of the 1,6-diaminohexane derivative, this results in coordination polymers where the Ti-2((OPr)-Pr-i)(8) units are interconnected by the diamine.
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页码：232 / 236
页数：5
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