Electrochemical and electrochromic properties of novel nanoporous NiO/V2O5 hybrid film

被引：67
|
作者：
Liu, Yanning [1 ]
Jia, Chunyang [1 ]
Wan, Zhongquan [1 ]
Weng, Xiaolong [1 ]
Xie, Jianliang [1 ]
Deng, Longjiang [1 ]
机构：
[1] Univ Elect Sci & Technol China, Sch Microelect & Solid State Elect, Natl Engn Res Ctr Electromagnet Radiat Control Ma, State Key Lab Elect Thin Films & Integrated Devic, Chengdu 610054, Peoples R China
来源：
SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2015年 / 132卷
基金：
中国国家自然科学基金;
关键词：
Electrochromism; Vanadium pentoxide; Nickel oxide; Hybrid film; Chemical deposition; Electrodeposition; VANADIUM-OXIDE; THIN-FILMS; OPTICAL-PROPERTIES; NICKEL-OXIDE; SOL-GEL; PENTOXIDE; FABRICATION; ELECTRODES; BEHAVIOR;
D O I：
10.1016/j.solmat.2014.09.033
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Nanoporous NiO/V2O5 hybrid film has been successfully prepared by combining chemical bath deposition (CBD) and electrochemical deposition methods. The electrochemical and optical properties of the hybrid film were investigated by cyclic voltammetry (CV), amperometric i-t, UV-vis spectroscopy and colorimetry analysis. Compared with single V2O5 electrochromic film, the NiO/V2O5 hybrid electrochromic film reveals reasonably good cyclic stability, better transmittance modulation (35% at 776 nm) and higher coloration efficiency (30.6 C-1 cm(2) at 776 nm). The noticeably improved electrochromic properties are mainly attributed to the introduction of NiO polycrystal substrate with nanoflake-like structure, which helps strengthen the structural stability of V2O5 film and improve the performance of Li+ ions intercalation/deintercalation. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：467 / 475
页数：9
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