Present and future synthesis challenges for zeolites

被引:91
作者
Coronas, Joaquin [1 ,2 ]
机构
[1] Univ Zaragoza, Chem & Environm Engn Dept, Zaragoza 50018, Spain
[2] Univ Zaragoza, Nanosci Inst Aragon, Zaragoza 50018, Spain
关键词
Zeolite; Zeolitic material; Mesoporous silica; Porous-tailored material; Zeolite membrane; MATERIAL DISSOLUTION TECHNIQUE; STRUCTURE-DIRECTING AGENTS; OF-THE-ART; MFI-ZEOLITE; MOLECULAR-SIEVE; MESOPOROUS SILICA; HIGH-THROUGHPUT; HYDROTHERMAL SYNTHESIS; POROUS MATERIALS; ZSM-5; MEMBRANES;
D O I
10.1016/j.cej.2009.11.006
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This work seeks to establish possible synthesis challenges in the zeolitic material field over the coming years. The choice may be subjective but it is worth reflecting on such an important question. The most pressing synthesis challenges in the opinion of the authors described in the following pages are: (1) elucidation of the nucleation and growth mechanism of zeolites; (2) controlling zeolite crystal size and growth habit; (3) preparation of extra-large pore zeolites; (4) synthesis of zeolitized mesoporous materials; (5) synthesis of chiral zeolites; (6) preparation and modification of layered zeolites; (7) and preparation of true molecular sieve membranes. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:236 / 242
页数:7
相关论文
共 157 条
[21]   Layered silicates by swelling of AMH-3 and nanocomposite membranes [J].
Choi, Sunho ;
Coronas, Joaquin ;
Jordan, Edgar ;
Oh, Weontae ;
Nair, Sankar ;
Onorato, Frank ;
Shantz, Daniel F. ;
Tsapatsis, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (03) :552-555
[22]   ORGANIC ION-EXCHANGE OF ZSM-5 ZEOLITE [J].
CHU, P ;
DWYER, FG .
ZEOLITES, 1988, 8 (05) :423-426
[23]   Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation [J].
Chung, Tai-Shung ;
Jiang, Lan Ying ;
Li, Yi ;
Kulprathipanja, Santi .
PROGRESS IN POLYMER SCIENCE, 2007, 32 (04) :483-507
[24]   Experimental study and numerical simulation of hydrogen/isobutane permeation and separation using MFI-zeolite membrane reactor [J].
Ciavarella, P ;
Moueddeb, H ;
Miachon, S ;
Fiaty, K ;
Dalmon, JA .
CATALYSIS TODAY, 2000, 56 (1-3) :253-264
[25]   Amorphous microporous molecular sieves with different pore dimensions and topologies:: Synthesis, characterization and catalytic activity [J].
Corma, A ;
Díaz-Cabañas, MJ .
MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 89 (1-3) :39-46
[26]   Optimisation of olefin epoxidation catalysts with the application of high-throughput and genetic algorithms assisted by artificial neural networks (softcomputing techniques) [J].
Corma, A ;
Serra, JM ;
Serna, P ;
Valero, S ;
Argente, E ;
Botti, V .
JOURNAL OF CATALYSIS, 2005, 229 (02) :513-524
[27]   Issues in the synthesis of crystalline molecular sieves: Towards the crystallization of low framework-density structures [J].
Corma, A ;
Davis, ME .
CHEMPHYSCHEM, 2004, 5 (03) :304-313
[28]   State of the art and future challenges of zeolites as catalysts [J].
Corma, A .
JOURNAL OF CATALYSIS, 2003, 216 (1-2) :298-312
[29]   ITQ-18 a new delaminated stable zeolite [J].
Corma, A ;
Fornés, V ;
Díaz, U .
CHEMICAL COMMUNICATIONS, 2001, (24) :2642-2643
[30]   Electrostatic and covalent immobilisation of enzymes on ITQ-6 delaminated zeolitic materials [J].
Corma, A ;
Fornés, V ;
Jordá, JL ;
Rey, F ;
Fernandez-Lafuente, R ;
Guisan, JM ;
Mateo, B .
CHEMICAL COMMUNICATIONS, 2001, (05) :419-420