Stabilization of high-valent terminal-oxo complexes: Interplay of d-orbital occupancy and coordination geometry

被引：21

作者：

Fackler, NLP

Zhang, SS

OHalloran, TV

机构：

[1] NORTHWESTERN UNIV,DEPT CHEM,EVANSTON,IL 60208

[2] NORTHWESTERN UNIV,DEPT BIOCHEM MOLEC BIOL & CELL BIOL,EVANSTON,IL 60208

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1996年 / 118卷 / 02期

关键词：

D O I：

10.1021/ja953051i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：481 / 482

页数：2

共 8 条

[1] Stabilizaiton of high-valent terminal-oxo complexes: Interplay of d-orbital occupancy and coordination geometry
J Am Chem Soc, 2 (481):
[2] Coordination chemistry and C-H bond reactivity of high-valent iron-oxo complexes
Que, Lawrence, Jr.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
[3] HIGH-VALENT ORGANOURANIUM COMPLEXES CONTAINING TERMINAL OXO FUNCTIONAL-GROUPS - A COMPARATIVE-STUDY
ARNEY, DSJ
BURNS, CJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 459 - INOR
[4] SYNTHESIS AND PROPERTIES OF HIGH-VALENT ORGANOURANIUM COMPLEXES CONTAINING TERMINAL ORGANOIMIDO AND OXO FUNCTIONAL-GROUPS - A NEW CLASS OF ORGANO-F-ELEMENT COMPLEXES
ARNEY, DSJ
BURNS, CJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (37) : 9448 - 9460
[5] Effedcts d-orbital occupancy on the geometry of the trigonal-bipyramidal complexes [MIICl3(Hdabco)(dabco)]n,where M is Mn, Co, Ni or Cu and dabco is 1,4-diazabicyclo[2.2.2]-octane
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Ali, Majid
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ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2006, 62 : M507 - M509
[6] TRANSITION-METAL COMPLEXES WITH SULFUR LIGANDS .57. STABILIZATION OF HIGH-VALENT FE(IV) CENTERS AND VACANT COORDINATION SITES BY SULFUR PI-DONATION - SYNTHESES, X-RAY STRUCTURES, AND PROPERTIES OF [FE(S2)2(PME3)N] (N = 1, 2) AND (NME4)[FE(S2)2(PME3)2].CH3OH (S2(2-) = 1,2-BENZENEDITHIOLATE(2-))
SELLMANN, D
GECK, M
KNOCH, F
RITTER, G
DENGLER, J
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (10) : 3819 - 3828
[7] Transition-metal complexes with sulfur ligands. 57. Stabilization of high-valent Fe(IV) centers and vacant coordination sites by sulfur π-donation. Syntheses, X-ray structures, and properties of [Fe('S2')2(PMe3)n] (n = 1, 2) and (NMe4)[Fe('S2')2(PMe3)2]·CH3OH ('S2'2- = 1,2-benzenedithiolate(2-))
1600, (113):
[8] Transition-metal complexes with sulfur ligands. 57. Stabilization of high-valent Fe(IV) centers and vacant coordination sites by sulfur π-donation. Syntheses, X-ray structures, and properties of [Fe('S2')2(PMe3)n] (n = 1,2) and (NMe4)[Fe('S2')2(PMe3)2]+CH3OH ('S2'2- = 1,2-benzenedithiolate(2-))
1600, (114):

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