Synthesis of highly crystalline hexagonal cesium tungsten bronze nanoparticles by flame-assisted spray pyrolysis

被引:36
作者
Hirano, Tomoyuki [1 ]
Nakakura, Shuhei [1 ,2 ]
Rinaldi, Febrigia Ghana [1 ]
Tanabe, Eishi [3 ]
Wang, Wei-Ning [4 ]
Ogi, Takashi [1 ]
机构
[1] Hiroshima Univ, Grad Sch Engn, Dept Chem Engn, 1-4-1 Kagamiyama, Higashihiroshima, Hiroshima 7398527, Japan
[2] Sumitomo Met Min Co Ltd, Ichikawa Res Ctr, 3-18-5 Nakakokubun, Ichikawa 2728588, Japan
[3] Hiroshima Prefectural Inst Ind Sci & Technol, 3-10-31 Kagamiyama, Higashihiroshima, Hiroshima 7390046, Japan
[4] Virginia Commonwealth Univ, Dept Mech & Nucl Engn, Richmond, VA 23219 USA
关键词
Tungsten bronze; Cs0.32WO3; Near-infrared absorption; Gas phase; Aerosol; NEAR-INFRARED ABSORPTION; PHOTOCATALYTIC ACTIVITY; HIGH-PERFORMANCE; STABILITY; PRECURSOR; REACTOR; FILMS; GAN;
D O I
10.1016/j.apt.2018.07.001
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Highly crystalline and hexagonal single-phase cesium tungsten bronze (Cs0.32WO3) nanoparticles were successfully synthesized by a flame-assisted spray pyrolysis followed by annealing under a reducing gas atmosphere. The resulting Cs0.32WO3 nanoparticles featured a pure hexagonal Cs0.32WO3 phase with a high crystallinity and homogeneous chemical composition. Unlike conventional methods, the proposed process in this paper has several advantages, including a short reaction time and the ability to yield products with high purity and good energy efficiency. Furthermore, the Cs0.32WO3 nanoparticles produced in this research showed a remarkable near-infrared shielding ability with a 97.7% cut-off at 1500 nm. (C) 2018 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.
引用
收藏
页码:2512 / 2520
页数:9
相关论文
共 30 条
[1]   Chromatic instabilities in cesium-doped tungsten bronze nanoparticles [J].
Adachi, Kenji ;
Ota, Yosuke ;
Tanaka, Hiroyuki ;
Okada, Mika ;
Oshimura, Nobumitsu ;
Tofuku, Atsushi .
JOURNAL OF APPLIED PHYSICS, 2013, 114 (19)
[2]   Flame-made WO3/TiO2 nanoparticles:: Relation between surface acidity, structure and photocatalytic activity [J].
Akurati, Kranthi K. ;
Vital, Andri ;
Dellemann, Jean-Philippe ;
Michalow, Katarzyna ;
Graule, Thomas ;
Fetti, Davide ;
Baiker, Alfons .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2008, 79 (1-2) :53-62
[3]   Tailored synthesis of macroporous Pt/WO3 photocatalyst with nanoaggregates via flame assisted spray pyrolysis [J].
Arutanti, Osi ;
Arif, Aditya Farhan ;
Balgis, Ratna ;
Ogi, Takashi ;
Okuyama, Kikuo ;
Iskandar, Ferry .
AICHE JOURNAL, 2016, 62 (11) :3864-3873
[4]   Controllable Crystallite and Particle Sizes of WO3 Particles Prepared by a Spray-Pyrolysis Method and Their Photocatalytic Activity [J].
Arutanti, Osi ;
Ogi, Takashi ;
Nandiyanto, Asep Bayu Dani ;
Iskandar, Ferry ;
Okuyama, Kikuo .
AICHE JOURNAL, 2014, 60 (01) :41-49
[5]   Core-shell structured CsxWO3@ZnO with excellent stability and high performance on near-infrared shielding [J].
Chen, Yunxiang ;
Zeng, Xianzhe ;
Zhou, Yijie ;
Li, Rong ;
Yao, Heliang ;
Cao, Xun ;
Jin, Ping .
CERAMICS INTERNATIONAL, 2018, 44 (03) :2738-2744
[6]   Synthesis of visible light-active nanostructured TiOx (x < 2) photocatalysts in a flame aerosol reactor [J].
Dhumal, Swapnil Y. ;
Daulton, Tyrone L. ;
Jiang, Jingkun ;
Khomami, Bamin ;
Biswas, Pratim .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 86 (3-4) :145-151
[7]   Fabrication of superhydrophobic and heat-insulating antimony doped tin oxide/polyurethane films by cast replica micromolding [J].
Feng Jie ;
Huang Baoyuan ;
Zhong Mingqiang .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2009, 336 (01) :268-272
[8]   COLOR IN TUNGSTEN TRIOXIDE THIN-FILMS [J].
GERARD, P ;
DENEUVILLE, A ;
HOLLINGER, G ;
DUC, TM .
JOURNAL OF APPLIED PHYSICS, 1977, 48 (10) :4252-4255
[9]   Simple route to (NH4)xWO3 nanorods for near infrared absorption [J].
Guo, Chongshen ;
Yin, Shu ;
Dong, Qiang ;
Sato, Tsugio .
NANOSCALE, 2012, 4 (11) :3394-3398
[10]   Facile synthesis of homogeneous CsxWO3 nanorods with excellent low-emissivity and NIR shielding property by a water controlled-release process [J].
Guo, Chongshen ;
Yin, Shu ;
Yan, Mei ;
Sato, Tsugio .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (13) :5099-5105