Iron Oxide/Polymer-Based Nanocomposite Material for Hydrogen Sulfide Adsorption Applications

被引:13
作者
Blatt, Oliver [1 ]
Helmich, Martin [2 ]
Steuten, Bastian [2 ]
Hardt, Sebastian [1 ]
Bathen, Dieter [2 ,3 ]
Wiggers, Hartmut [1 ,4 ]
机构
[1] Univ Duisburg Essen, Inst Combust & Gas Dynam React Fluids, IVG, D-47057 Duisburg, Germany
[2] Univ Duisburg Essen, Chair Thermal Separat Technol, D-47057 Duisburg, Germany
[3] Inst Energy & Environm Technol IUTA, Duisburg, Germany
[4] Univ Duisburg Essen, Ctr Nanointegrat Duisburg Essen, CENIDE, D-47057 Duisburg, Germany
关键词
Adsorption; Hydrogen sulfide removal; Iron oxide; Nanocomposite; Nanoparticles; PARTICLES; REMOVAL; WATER; SIZE; H2S;
D O I
10.1002/ceat.201400303
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The processing of iron oxide nanoparticles derived from spray flame synthesis for specific adsorption applications is described. After the as-prepared particles proved the ability for H2S removal in pure gas treatment, two different nanoparticle-based composite materials were prepared. While impregnation of activated carbon with the as-prepared nanoparticles showed the expected increase in H2S adsorption capacities, a significant enhancement in desulfurization performance was observed for a novel iron oxide nanoparticle composite material. H2S adsorption was tested in fixed-bed breakthrough curve measurements. The H2S removal efficiency of the novel material under ambient conditions indicates highly promising properties for potential use in industrial and air pollution control applications.
引用
收藏
页码:1938 / 1944
页数:7
相关论文
共 32 条
[1]  
[Anonymous], OIL GAS J
[2]  
[Anonymous], CAMPBELL PETROLEUM S
[3]  
[Anonymous], 2010, 9277201009 ISO
[4]  
[Anonymous], IR SPECTR IR 2 SULF
[5]   On the mechanism of hydrogen sulfide removal from moist air on catalytic carbonaceous adsorbents [J].
Bagreev, A ;
Bandosz, TJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (03) :530-538
[6]   A role of sodium hydroxide in the process of hydrogen sulfide adsorption/oxidation on caustic-impregnated activated carbons [J].
Bagreev, A ;
Bandosz, TJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (04) :672-679
[7]   On the adsorption/oxidation of hydrogen sulfide on activated carbons at ambient temperatures [J].
Bandosz, TJ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 246 (01) :1-20
[8]  
Baraton M.-I., 2003, NANOTECHNOLOGY BOOK, V11
[9]   Synthesis, Characterization, and Variable Range Hopping Transport of Pyrite (FeS2) Nanorods, Nanobelts, and Nanoplates [J].
Caban-Acevedo, Miguel ;
Liang, Dong ;
Chew, Kit S. ;
DeGrave, John P. ;
Kaiser, Nicholas S. ;
Jin, Song .
ACS NANO, 2013, 7 (02) :1731-1739
[10]   Adsorption characteristics of alkaline activated carbon exemplified by water vapor, H2S, and CH3SH gas [J].
Chiang, HL ;
Tsai, JH ;
Tsai, CL ;
Hsu, YC .
SEPARATION SCIENCE AND TECHNOLOGY, 2000, 35 (06) :903-918