Transition metal alloys and compounds;
Crystal growth;
Magnetization;
Phase transitions;
Magnetic measurements;
NEUTRON-DIFFRACTION;
REFINEMENT;
FE2GES4;
NUCLEAR;
D O I:
10.1016/j.jmmm.2019.166164
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
Single crystals of Mn2GeS4 were grown by chemical vapor transport. X-ray powder diffraction data show a single phase. Rietveld refinement results indicated that Mn2GeS4 crystalize in an olivine-type structure. The magnetic properties of the compound have been studied by means of DC magnetometry and AC susceptibility measurements. The system shows two different phase transitions on decreasing temperature, a first one at about 90 K, leading the system from the paramagnetic to an antiferromagnetic state and a second at about 25 K, corresponding to the onset of a weak ferromagnetic behavior superimposed to the underlying antiferromagnetic order. No evidence of a possible spin-glass behavior in the intermediate temperature region has been found.
机构:
Russian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, RussiaRussian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, Russia
Makarova, I. P.
Grebenev, V. V.
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Russian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, RussiaRussian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, Russia
Grebenev, V. V.
Vasil'ev, I. I.
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Russian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, RussiaRussian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, Russia
Vasil'ev, I. I.
Dmitricheva, E. V.
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Russian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, RussiaRussian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, Russia
Dmitricheva, E. V.
Komornikov, V. A.
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Russian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, RussiaRussian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, Russia
Komornikov, V. A.
Dolbinina, V. V.
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Russian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, RussiaRussian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, Russia
Dolbinina, V. V.
Mikheikin, A. S.
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机构:
European Synchrotron Radiat Facil, Swiss Norwegian Beamlines, Rue Jules Horowitz 6, F-38000 Grenoble, France
Southern Fed Univ, Fac Phys, Ul Zorge 5, Rostov Na Donu 344000, RussiaRussian Acad Sci, AV Shubnikov Crystallog Inst, Leninskii Pr 59, Moscow 119333, Russia